Graft polymerization of vinyl monomers on the surface of solid inorganic materials photoinitiated by the systems RCCl3-carbonyls of transition metals

Andrianov, Alexander K.; Olenin, A. V.; Saprygin, O.N.; Garina, Ye.S.; Zubov, V.P.; Кашутина, Е. А.; Zhdanov, A. A.

doi:10.1016/0032-3950(84)90436-2

Cited by 2 publications

(2 citation statements)

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“…The surface modification of silica gel and Aerosil by the (methyidichlorosilyl)propyl ester of trichloroacetic acid led to halide functionalized organosilicas, which were further utilized by Mn 2 (CO) 10 ‐based visible‐light‐initiated free radical polymerization of MMA and St. The grafting degree and molecular weight of the grafted PMMA were increased by increasing polymerization time and concentrations of Mn 2 (CO) 10 and CCl 3 groups …”

Section: Synthetic Applicationsmentioning

confidence: 99%

“…The grafting degree and molecular weight of the grafted PMMA were increased by increasing polymerization time and concentrations of Mn 2 (CO) 10 and CCl 3 groups. 112 A bromine functionalized polydimethylsiloxane (PDMS) surface was simply prepared by mixing a vinyl-terminated initiator, undec-10-enyl-2-bromo-2-methylpropanoate, poly(dimethylmethylvinylsiloxane) base and a curing agent of Sylgard 184 in the presence of platinum catalyst. Mixing together the hydrosilylation reaction between the vinyl groups and the hydrosilane hydrogens results in crosslinked bromine functional PDMS networks.…”

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confidence: 99%

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Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Çiftçi

Taşdelen

Yaǧcı

2016

Polymer International

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The environmentally friendly Mn 2 (CO) 10 -based visible light photoinitiating system is a powerful method for the preparation of linear and crosslinked polymeric structures. From a practical point of view, the most important feature of this initiating system is its optical characteristics in the visible range with high quantum yield and good solubility properties. This photoinitiating system is applicable for a variety of monomers that can be polymerized via either radical or cationic mechanisms. Various complex macromolecular structures such as telechelic polymers, block and graft copolymers, polymer networks and surface modifications can be simply prepared by using halogenated precursors. This photoinitiating system is also combined with controlled radical polymerization techniques providing a mild and efficient method for polymer synthesis.

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Section: Synthetic Applicationsmentioning

confidence: 99%

mentioning

confidence: 99%

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Çiftçi

Taşdelen

Yaǧcı

2016

Polymer International

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Grafting kinetics of poly(methyl methacrylate) on microparticulate silica

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Oosterling

Challa

et al. 1990

Polymer

137

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Grafting of poly(methyl methacrylate) (PMMA) on microparticulate silica was achieved by initiating the polymerization of MMA by 4,4'-azobis(4-cyanopentanoic acid) that was covalently bound to the silica surface. The initiator seems to be destabilized upon binding it to the silica surface. The kinetics of the graft polymerization are described and are largely affected by the Trommsdorff effect, which makes it possible to graft a high amount of PMMA on silica.

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Graft polymerization of vinyl monomers on the surface of solid inorganic materials photoinitiated by the systems RCCl3-carbonyls of transition metals

Cited by 2 publications

References 6 publications

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Grafting kinetics of poly(methyl methacrylate) on microparticulate silica

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Graft polymerization of vinyl monomers on the surface of solid inorganic materials photoinitiated by the systems RCCl3-carbonyls of transition metals

Cited by 2 publications

References 6 publications

Macromolecular design and application using Mn2(CO)10‐based visible light photoinitiating systems

Macromolecular design and application using Mn2(CO)10‐based visible light photoinitiating systems

Grafting kinetics of poly(methyl methacrylate) on microparticulate silica

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Product

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Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems