Gold(III) dithiocarbamate derivatives of N-methylglycine: An experimental and theoretical investigation

Synthesis, characterization and in vitro cytotoxicity of palladium(II) complexes with mixed ligands. X‐ray diffraction study of C31H36ClNPPdS2

“…35 In the case of a monodentate dithiocarbamate ligand, a doublet arises around 950-990 cm −1 due to non-equivalence of C-S stretching vibrations, whereas in the case of a bidentate ligand, only one band appears in the investigated region, which is indicative of a symmetrically bound dithiocarbamate moiety. 36 In the present series of Pd(II) complexes, only one strong band was observed in the region 1000-1099 cm −1 , which indicates the υ(SCS) vibrational mode and suggests a bidentate symmetrical behavior of the dithiocarbamate moiety.…”

Rational design of gold(III)-dithiocarbamato peptidomimetics for the targeted anticancer chemotherapy

“…Finally, esterification of the C-terminus was proved necessary because it was previously shown that analogues containing a free carboxylic functional group are not active [44]. Additionally, although conferring less water solubility, the bulky t-butyl group is unlikely to undergo easy hydrolysis (occurring only in strongly acidic conditions), thus providing stability to the final compounds and, consequently, avoiding intramolecular cyclization of the peptide chain.…”

Potent inhibitory effects of benzyl and p-xylidine-bis dithiocarbamate sodium salts on activities of mushroom tyrosinase

“…Dithiocarbamates are versatile classes of chelating compounds that have been developed in the last 40-50 years. They are an integral part of industrialized agriculture and medicine, and are used against a broad spectrum of fungi and plant diseases caused by fungi 45 . Dithiocarbamates are used in health care for the management of alcoholism, and have been applied to prevent arthrosclerosis, and for antimicrobial and anti-inflammatory activity and metal transport in membranes 46 .…”