“…[4][5][6] In the case of GaAs, Au-free NW growth has been obtained for selected substrate and growth conditions, with Ga nanoparticles found at the tip of the resulting NWs. [7][8][9][10][11][12][13][14] Using a VLS-like model, NW growth has been associated with the formation of Ga nanoparticles, which promote one-dimensional growth. [7][8][9][10][11][12][13][14] An important general feature of GaAs NWs obtained by Ga-assisted growth is their prevalent zincblende (ZB) crystal structure, 9,10,13,14 in contrast with the wurtzite (WZ) structure commonly observed during Au-catalyzed growth.…”