Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor

Guo, Xiaohui; Li, Yong; Song, Wei; Shen, Wenjie

doi:10.1007/s10562-011-0642-y

Cited by 52 publications

(48 citation statements)

References 30 publications

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“…In accord with our results, it was recently reported that the addition of Re to a Pd catalyst leads to formation of Re-Pd bimetallic particles which shows an increased conversion of glycerol and a higher selectivity to propanediols compared with the that of mono-component Pd catalysts [26]. At the same time, Co-Zn-Al [27] and RuFe/CNT [28] catalysts, were found to be highly active and stable towards the hydrogenolysis of polyols suggesting that the addition of Co and Fe as cometals can increase the activity of Pd catalysts in glycerol CTH.…”

Section: Catalytic Testssupporting

confidence: 92%

Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol

Mauriello

Ariga

Musolino

et al. 2015

Applied Catalysis B: Environmental

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The transfer hydrogenolysis of glycerol promoted by supported palladium catalysts is reported. The reactions were carried out under mild conditions (453 K and 5 bar of N 2 ) in absence of added hydrogen by using the reaction solvent, 2-propanol, as hydrogen source. The catalytic results are interpreted in terms of metal (Pd) -metal (Co or Fe) interaction that modifies the electronic properties of palladium and affords bimetallic PdM sites (M = Co or Fe), thus enhancing the catalytic properties of the systems in the conversion of glycerol as well as in the selectivity to 1,2-propanediol and 1-propanol. The transfer hydrogenolysis mechanism is here elucidated and involves the glycerol dehydration to 1-hydroxyacetone and the subsequent hydrogenation of 1-hydroxyacetone to propylene glycol.3

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Section: Catalytic Testssupporting

confidence: 92%

Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol

Mauriello

Ariga

Musolino

et al. 2015

Applied Catalysis B: Environmental

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“…95%. Co and Ni also show catalytic activity for 1,2-PDO formation from glycerol, whereas the selectivity to 1,2-PDO is lower than that of Cu because Co and Ni promote the C-C cleavage and increase ethylene glycol and/or ethanol selectivity [98,99]. In the glycerol hydrogenolysis over Among the three base metals, Cu shows the highest activity for 1,2-PDO formation.…”

Section: Reaction Route Of Glycerol Hydrogenolysis Into 12-propanediolmentioning

confidence: 98%

“…Because of the competitive formation of glycerol C-C cleavage products, such as methanol, ethanol and ethylene glycol, 1,2-PDO cannot be selectively produced over Co-and Ni-based catalysts [98,99]. The 1,2-PDO selectivities higher than 90% can be achieved over most of the Cu-supported catalysts [90][91][92][93][94][95][96][97], and Cu with small particle sizes is preferable for 1,2-PDO formation [91][92][93][95][96][97].…”

Section: Liquid-phase Glycerol Hydrogenolysis Into 12-pdo Over Base mentioning

confidence: 99%

Glycerol hydrogenolysis into useful C3 chemicals

Sun

Yamada

Sato

et al. 2016

Applied Catalysis B: Environmental

263

161

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Applications of renewable biomass provide facile routes to alleviate the shortage of fossil fuels as well as to reduce the emission of CO 2. Glycerol, which is currently produced as a waste in the biodiesel production, is one of the most attractive biomass resources. In the past decade, the conversion of glycerol into useful chemicals has attracted much attention, and glycerol is mainly converted by steam reforming, hydrogenolysis, oxidation, dehydration, esterification, carboxylation, acetalization, and chlorination. In this review, we focused on the catalytic hydrogenolysis of glycerol into C3 chemicals, which contain many industrially important products such as 1,2-propanediol, 1,3-propanediol, allyl alcohol, 1-propanol and propylene. In the hydrogenolysis of glycerol into propanediols, advantages and disadvantages of liquid-and vapor-phase reactions are compared. In addition, recent studies on catalysts, reaction conditions, and proposed pathways are primarily summarized and discussed. Furthermore, new research trends are introduced in connection with the hydrogenolysis of glycerol into allyl alcohol, propanols and propylene.

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“…In addition to Cu catalysts, there are studies showing that Raney nickel (182), Ni/AC (183), Ni/NaX (184), Ni/SiO 2 -Al 2 O 3 (185), Co/MgO (186), Ni/Mg/Al, Ni/Co/Mg/Al, and Co/Zn/Al layered double hydroxides (180,187) had relatively good activity in the hydrogenolysis of glycerol to 1,2-propanediol (Table 2). Particularly, in the presence of a Raney nickel catalyst using crude glycerol from biodiesel production as the feedstock for the hydrogenolysis was found to be possible (182).…”

Section: Supported Cu and Ni Catalystsmentioning

confidence: 99%

Recent Advances in Catalytic Conversion of Glycerol

Zhou¹,

Zhao²,

Tong³

et al. 2013

Catalysis Reviews

177

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The article underlines and discusses the state-of-the-art accomplishments in the catalytic conversion of glycerol (1,2,3-propanetriol) to fuels and value-added chemicals in the past five years (2008)(2009)(2010)(2011)(2012). The reactions include steam reforming, aqueous-phase reforming, hydrogenolysis, oxidation, dehydration, esterification, etherification, carboxylation, acetalization, and chlorination. Typical products are hydrogen, propanediols, dihydroxyacetone, glyceric acid, acrolein, glyceride, polyglycerol, glycerol carbonate, acetals, ketals, and epichlorohydrine. Recent studies on the catalysts, reaction conditions, and possible pathways are primarily discussed. They indicate that major breakthroughs are achieved by the use of multifunctional catalysts, process intensification and integrated reactions. Literature survey suggests that future work on the catalytic conversion of glycerol for commercial goals particularly requires new catalysts, innovative reactor engineering, and close multidisciplinary partnership.

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Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor

Cited by 52 publications

References 30 publications

Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol

Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol

Glycerol hydrogenolysis into useful C3 chemicals

Recent Advances in Catalytic Conversion of Glycerol

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