Glow discharge polymerization—II α-methylstyrene, ω-methylstyrene and allylbenzene

Denaro, A.R.; Owens, P.A.; Crawshaw, A.

doi:10.1016/0014-3057(69)90076-7

Cited by 49 publications

(9 citation statements)

References 6 publications

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“…Studies on the synthesis of various organics using glow discharge were first published by German scientists in the 1960s [ 6 , 7 , 8 , 9 ]. Afterwards, the first applications using these plasma polymers were reported by Goodman [ 10 ], and subsequent studies on the property improvements of materials using plasma polymers were actively conducted, with a focus on the interaction between plasma and various substances [ 11 , 12 , 13 , 14 , 15 , 16 ]. Today, plasma synthesis is selected for various applications, such as layer deposition for electrical devices [ 17 , 18 , 19 , 20 ], antibio- or bio-material applications [ 21 , 22 , 23 , 24 ], and surface modification [ 25 , 26 , 27 , 28 ], among others.…”

Section: Introductionmentioning

confidence: 99%

A Review of Plasma Synthesis Methods for Polymer Films and Nanoparticles under Atmospheric Pressure Conditions

et al. 2021

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In this paper, we present an overview of recent approaches in the gas/aerosol-through-plasma (GATP) and liquid plasma methods for synthesizing polymer films and nanoparticles (NPs) using an atmospheric-pressure plasma (APP) technique. We hope to aid students and researchers starting out in the polymerization field by compiling the most commonly utilized simple plasma synthesis methods, so that they can readily select a method that best suits their needs. Although APP methods are widely employed for polymer synthesis, and there are many related papers for specific applications, reviews that provide comprehensive coverage of the variations of APP methods for polymer synthesis are rarely reported. We introduce and compile over 50 recent papers on various APP polymerization methods that allow us to discuss the existing challenges and future direction of GATP and solution plasma methods under ambient air conditions for large-area and mass nanoparticle production.

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Section: Introductionmentioning

confidence: 99%

A Review of Plasma Synthesis Methods for Polymer Films and Nanoparticles under Atmospheric Pressure Conditions

et al. 2021

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“…The properties of a plasma‐deposited polymer are affected by many deposition factors that in turn affect the final quality of nanofilms . Among them, the effect of the driving frequency and the magnetic confinement are considered central …”

Section: Introductionmentioning

confidence: 99%

“…In the proposed mechanism, the glow discharge contains a mixture of dissociated monomers (radicals, di‐radicals) and un‐dissociated monomers that can lead to two cycles of polymerization initiated either by radicals or by di‐radicals. As a consequence, the resulting plasma polymer is characterized by a high content of radicals in the form of dangling bonds and/or free radicals …”

Section: Introductionmentioning

confidence: 99%

The Effect of Low Pressure Plasma Polymerization Modes on the Properties of the Deposited Plasma Polymers

Zeniieh

Rostas

Schleicher

et al. 2016

Plasma Process. Polym.

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This work characterizes the properties of deposited plasma polymer that has been generated using three different low-pressure, low-temperature plasma modes: magnetron-enhanced audio frequency (15 kHz), magnetron-enhanced radio frequency (13.56 MHz), and radio frequency (13.56 MHz). A correlation between the applied plasma modes, the concentration of generated radicals in the deposited nanofilms, and the radical decay kinetics was found and is discussed. In addition, the role of the plasma driving frequency with respect to the properties of the films, in particular their density and their barrier properties, has been elucidated.

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“…Aromatic compounds such as benzene, toluene, xylene, styrene, etc, were chosen for this purpose. [2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19] These compounds, however, were subjected to ring-opening reactions in a discharge state and yielded plasma polymers containing alkyl chains rather than aromatic groups. This unexpected evidence in these plasma polymerizations may be the result of activation processes by the action of plasma.…”

Section: Introductionmentioning

confidence: 99%

Plasma polymerization of phenylsilane

Inagaki

Hirao

1986

J. Polym. Sci. A Polym. Chem.

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Comparative studies on plasma polymerizations of phenylsilane (PhSiH3) and toluene (PhCH3) have been carried out to prepare plasma polymers containing aromatic groups. The IR and ESCA spectra show that PhSiH3 and PhCH3 are subjected to ring‐opening reactions in a discharge state to form polymers involving alkyl chains as well as aromatic groups. The ring‐opening reactions are more feeble in the PhSiH3 system than in the PhCH3 system, which may be due to stabilization of phenyl–Si bonds in PhSiH3 by contribution of pπ−dπ bonding. Aromatic groups incorporated into the plasma polymers from PhSiH3 are mono‐substituted.

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Glow discharge polymerization—II α-methylstyrene, ω-methylstyrene and allylbenzene

Cited by 49 publications

References 6 publications

A Review of Plasma Synthesis Methods for Polymer Films and Nanoparticles under Atmospheric Pressure Conditions

A Review of Plasma Synthesis Methods for Polymer Films and Nanoparticles under Atmospheric Pressure Conditions

The Effect of Low Pressure Plasma Polymerization Modes on the Properties of the Deposited Plasma Polymers

Plasma polymerization of phenylsilane

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