2019
DOI: 10.1007/s10955-019-02393-2
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Global Thermodynamics for Heat Conduction Systems

Abstract: We propose the concept of global temperature for spatially non-uniform heat conduction systems. With this novel quantity, we present an extended framework of thermodynamics for the whole system such that the fundamental relation of thermodynamics holds, which we call "global thermodynamics" for heat conduction systems. Associated with this global thermodynamics, we formulate a variational principle for determining thermodynamic properties of the liquid-gas phase coexistence in heat conduction, which correspond… Show more

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Cited by 16 publications
(26 citation statements)
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“…We will also see that θ is not necessarily equal to T c (p) because metastable states, such as super-cooled gas or super-heated liquid, may be stably observed in heat conduction. Moreover, this relation and other relations are consistent with those determined by the variational principle for heat conduction systems attached to two heat baths of T 1 and T 2 [31]. See Sec.…”
Section: S(h P N φ)supporting
confidence: 84%
See 3 more Smart Citations
“…We will also see that θ is not necessarily equal to T c (p) because metastable states, such as super-cooled gas or super-heated liquid, may be stably observed in heat conduction. Moreover, this relation and other relations are consistent with those determined by the variational principle for heat conduction systems attached to two heat baths of T 1 and T 2 [31]. See Sec.…”
Section: S(h P N φ)supporting
confidence: 84%
“…From this viewpoint, the liquid-gas phase coexistence in heat conduction has turned out to be a good target even in the linear response regime. Our previous papers predicted that the interface temperature deviates from the equilibrium transition temperature [30,31]. Numerical simulations have quantitatively confirmed this prediction [32].…”
Section: Introductionmentioning
confidence: 60%
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“…We have used these properties to measure with high accuracy the hard-disks equation of state in nonequilibrium simulations, obtaining excellent results even across the fluid-hexaticsolid transition regime. In particular, we have found an interesting nonequilibrium fluid/solid coexistence under a strong temperature gradient, a Stefan-like phenomenon which can be confronted with recent theoretical predictions [83][84][85][86] and calls for further investigation. Indeed, hints of the double phase transition in hard disks can be observed in the transport properties of the nonequilibrium fluid [32], a behavior that deserves further exploration.…”
Section: Discussion and Outlookmentioning
confidence: 69%