“…Simultaneously, CO2 is emitted 15 during arc volcanism and at mid-ocean ridges (MORs) where new oceanic crust is being created (Burton et al, 2013). Despite the proposal that silicate weathering has, at some stages, been a dominating control of atmospheric CO2 levels (Kump, 2000;Kent and Muttoni, 2013), arc magmatism at icehousegreenhouse transitions is thought to be the first-order control on climate fluctuations while silicate weathering acts to modulate atmospheric CO2 as a secondary regulative process (Ridgwell and Zeebe,20 2005; Lee and Lackey, 2015;McKenzie et al, 2016). Recent studies have found support for links between global arc activity and icehouse-greenhouse transitions using detrital zircon ages, modelling and experimental techniques, particularly as drivers of greenhouse conditions in the Cambrian (McKenzie et al, 2016;Cao et al, 2017), Jurassic-Cretaceous (McKenzie et al, 2016) and early Paleogene (Lee et al, 2013;Carter and Dasgupta, 2015;Cao et al, 2017).…”