We have grown a single crystal of La2−xSrxCuO4 in which the Sr concentration, x, continuously changes from 0.24 to 0.29 in the overdoped regime and obtained many pieces of single crystals with different x values by slicing the single crystal. From detailed measurements of the magnetic susceptibility, χ, of each piece, it has been found that the absolute value of χ at the measured lowest temperature 2 K, |χ2K|, on field cooling rapidly decreases with increasing x as well as the superconducting (SC) transition temperature. As the value of |χ2K| is regarded as corresponding to the SC volume fraction in a sample, it has been concluded that a phase separation into SC and normal-state regions occurs in a sample of La2−xSrxCuO4 in the overdoped regime.KEYWORDS: phase separation, La2−xSrxCuO4, magnetic susceptibility, Sr-concentration-gradient single crystal, superconducting volume fractionThe study of the electronic states of high-T c cuprates has been a central issue to elucidate the mechanism of high-T c superconductivity. Compared with the underdoped regime in which extensive studies have been carried out, physical properties in the overdoped regime have not been so clarified. The microscopic electronic inhomogeneity in the CuO 2 plane suggested from scanning-tunneling-microscopy (STM) measurements was a sensational observation.1 In optimally doped Bi 2 Sr 2 CaCu 2 O 8+δ (Bi-2212), it was suggested that both the local density of states and the superconducting (SC) gap were spatially inhomogeneous. Such electronic inhomogeneity was observed in slightly underdoped and overdoped Bi-2212 as well.2 However, the inhomogeneity in the CuO 2 plane has still been a controversial issue, because STM measurements are very sensitive to the surface electronic state, which may sometimes be rather different from the bulk one. In order to confirm the inhomogeneity, measurements reflecting bulk properties of a sample are absolutely required.As for the electronic inhomogeneity in the overdoped regime, transverse-field muon-spin-relaxation (µSR) measurements in the overdoped regime of Tl 2 Ba 2 CuO 6+δ revealed that the muon-spin depolarization rate in the ground state, regarded as being proportional to the SC carrier density divided by the effective mass, n s /m * , decreased with an increase in the hole concentration, p.3, 4 It was speculated that a microscopic phase separation into SC and normal-state regions occurred in the overdoped high-T c cuprates.5 Similar results were also obtained from the µSR measurements in the overdoped regime of (Y, Ca)Ba 2 Cu 3 O 7−δ (Y/Ca-123) and Tl 1−y Pb y Sr 2 Ca 1−y Y y Cu 2 O 7 .
6One conclusive way to prove the phase separation is to study the SC volume fraction. Formerly, Nagano et al. reported from measurements of the magnetic susceptibility, χ, in La 2−x Sr x CuO 4 (LSCO) that the shielding volume * E-mail address: adachi@teion.apph.tohoku.ac.jp fraction, obtained from χ at 4.2 K on zero-field cooling using a bulk sample, was almost 100% in the range 0.07 ≤ x ≤ 0.27.7 They insisted that the SC...