Abstract:Many materials are known to exist in several stable polymorphs, but synthesis only provides access to a subset. This situation is exemplified by the dichalcogenide semiconductor GeSe 2 . Besides the amorphous form, which attracted intense interest, crystalline GeSe 2 in the bulk and in nanostructures such as flakes and nanobelts invariably adopts the 2D/layered monoclinic β-phase. Hence, the properties of other polymorphs such as the orthorhombic 3D GeSe 2 phase remain unknown. Here, we report the high-yield s… Show more
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