2009
DOI: 10.1016/j.tca.2009.04.002
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Geopolymerization process of alkali–metakaolinite characterized by isothermal calorimetry

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Cited by 301 publications
(89 citation statements)
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“…The researches on the geopolymerization mechanism in this system are attracting more and more attentions, and the process may be summarized briefly as follows: dissolution, rearrangement, condensation and re-solidification [12][13][14][15][16][17][18]. The structure and mechanical properties of geopolymers are affected by several parameters such as chemical composition and reactivity of the raw materials, nature and concentration of the activating solution, curing conditions.…”
Section: Introductionmentioning
confidence: 99%
“…The researches on the geopolymerization mechanism in this system are attracting more and more attentions, and the process may be summarized briefly as follows: dissolution, rearrangement, condensation and re-solidification [12][13][14][15][16][17][18]. The structure and mechanical properties of geopolymers are affected by several parameters such as chemical composition and reactivity of the raw materials, nature and concentration of the activating solution, curing conditions.…”
Section: Introductionmentioning
confidence: 99%
“…Alkali hydroxides are usually combined with an aluminosilicate source in the form of an aqueous solution (Provis, 2009). Given the complexity of the gel structure, which is formed through silicate activation of fly ash or metakaolin, and in particular its dependence on a large number of compositional and processing parameters, various approaches to the analysis of the gel binder were developed and implemented in the past years (Rahier et al, 1997, Palomo et al, 2005, Yao et al, 2009.…”
Section: Introductionmentioning
confidence: 99%
“…P3 and P4, have lower total heats of reaction. These results can then be used to determine the relative geopolymerisation extents, as the process is entirely exothermic and so the heat of reaction provides a useful representation of the extent of geopolymerization [10,30].…”
Section: Exomentioning
confidence: 99%
“…It is assumed that the rate constant K is an inverse function of t 50 , so that the ratios of t 50 values determined at different temperatures can be used instead of K to calculate E a [30,33,35]. So, plotting Table 5 shows the calculated apparent activation energy of each of This is a preprint of an article published in Journal of Thermal Analysis and Calorimetry.…”
Section: Apparent Activation Energymentioning
confidence: 99%