Abstract. Among various definitions of quantum correlations, quantum discord has attracted considerable attention. The connection between the quantum discord and the entanglement of formation is described by Koashi-Winter relation. We investigate this relation from the viewpoint of the quantum channel that is isomorphic to the given state. It is shown that in the case of two-qubit states the channel, on the one hand, determines the form of the quantum steering ellipsoid of the given state, and on the other hand, is closely related to the concurrence of the complement state of the given state. We also point out that, for two-qubit rank-two state, von Neumann measurement is the optimal choice to achieve the quantum discord. However, for some two-qubit states with the rank larger than two, the three-element POVM measurement is optimal.