We report transport properties of single-crystalline Pd 3 Bi 2 S 2 , which has been predicted to host an unconventional electronic phase of matter beyond three-dimensional Dirac and Weyl semimetals. Similar to several topological systems, the resistivity shows field-induced metal to semiconductor-like crossover at low temperature. Large, anisotropic and non-saturating magnetoresistance has been observed in transverse experimental configuration. At 2 K and 9 T, the MR value reaches as high as ∼1.1×10 3 %. Hall resistivity reveals the presence of two types of charge carriers and has been analyzed using two-band model. In spite of the large density (> 10 21 cm −3 ), the mobility of charge carriers is found to be quite high (∼ 0.75×10 4 cm 2 V −1 s −1 for hole and ∼ 0.3×10 4 cm 2 V −1 s −1 for electron). The observed magneto-electrical properties indicate that Pd 3 Bi 2 S 2 may be a new member of the topological semimetal family, which can have a significant impact in technological applications.Topology protected electronic properties of materials have opened up a new arena of research in modern condensed matter physics 1-7 . These novel materials have generated immense research interest in fundamental physics of low-energy relativistic particles. In highenergy physics, the relativistic fermions are protected by Poincare symmetry, while in condensed matter, they respect one of the 230 space group symmetries (SGs) of the crystal. The variation of crystal symmetry from one material to another escalates the potential to explore free fermionic excitations such as Dirac, Weyl, Majorana and beyond. Besides fundamental interest, the discovery of topological insulators 1,2 , 3D Dirac and Weyl semimetals 3,4 , and Majorana fermions in superconducting heterostructures 5-7 have planted the seed of technological revolution in research and development of electronic devices. Fabrication of fast electronic devices, spintronics applications and fault tolerant quantum computing are the few among the several specific topics of interest. So, the prediction and experimental realization of new materials, which host such quasi-particle excitations, can have significant impact on paradigm shifting in technological application.Very recently, Bradlyn et al. 8 have predicted the existence of exotic fermions near the Fermi level in several materials, governed by their respective space group symmetry. Unlike two-and four-fold degeneracy in 3D Weyl/Dirac semimetals, these systems exhibit three-, six-, and eight-fold degenerate band crossing at high symmetry points in the Brillouin zone. It has been proposed that Pd 3 Bi 2 S 2 with space group 199 hosts three-fold degenerate fermion as the quasi-particle excitation due to the three-band crossing at the high symmetry P point, which is just 0.1 eV above the Fermi level 8 . So far, no magnetotransport experiment has been done on this material. The results are important not only for the fundamental research but also to manipulate them in technological application. In the present work, we have synthes...