Geometric constraints regulated regioselectivity: Pd-catalyzed α-deuteration of pyridines with secondary phosphine oxide
Chenxu Zheng,
Jiben Xue,
Zhi-Jiang Jiang
et al.
Abstract:A Pd-catalyzed regioselective H/D exchange at the α-position of pyridines has been achieved by employing secondary phosphine oxide as an internal base. The proposed five-membered structure enabled the reaction to...
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