Geographical controls and anthropogenic impacts on dissolved organic carbon from mountainous rivers: Insights from optical properties and carbon isotopes

Abstract

Abstract. Mountainous rivers (MRs) are one of the critical systems in transporting dissolved organic carbon (DOC) from terrestrial environments to downstream ecosystems. However, how geographical factors and anthropogenic impacts control the composition and export of DOC in mountainous rivers remains largely unclear. Here, we explore DOC dynamics in three subtropical mountainous catchments (i.e., the Yinjiang, Shiqian, and Yuqing catchments) in southwest China which are highly influenced by anthropogenic activities. Water chemistry, stable and radioactive carbon isotopes of DOC (δ13CDOC and Δ14CDOC) and optical properties (UV absorbance and fluorescence spectra) for river water were employed to assess the biogeochemical processes and controlling factors of DOC. The radiocarbon ages of the DOC in the Yinjiang River varied widely, ranging from 928 years before present to modern. Both allochthonous and autochthonous sources had an important effect on riverine DOC export. Results from carbon isotopes suggested that in-stream processing of POC is also an important source of DOC. DOC in catchments with higher slope gradients and lower annual air temperature was characterized by lower concentration and more aromatic, which was distinct from those with gentle slopes and higher temperature. Variabilities in DOC concentrations and δ13CDOC were also explained by land use, showing that higher DOC concentrations with 13C-depleted characters were observed in urban and agricultural land use areas. Moreover, DOM was less aromatic, less recently produced and had a higher degree of humification in catchments with a higher proportion of urban and agricultural land use area. This research highlights the significance of incorporating geographical controls and anthropogenic impacts into the MRs to better understand their DOC dynamics and quality of dissolved organic matter (DOM).

Radiocarbon signatures of carbon phases exported by Swiss rivers in the Anthropocene

“…Moreover, Chen et al . [ 83 ] recently suggested that even in mountainous rivers in-stream production and transformation of carbon exerts a significant influence on riverine DO 14 C dynamics. Riverine in-stream transformations can be separated into biotic (e.g.…”

“…primary and secondary production) or abiotic (e.g. absorption, desorption, photo-oxidation, dissolution) processes, which are each strongly controlled by river water temperature and residence time [ 33 , 35 , 83 ]. The significant positive relationship between DO 14 C and the long-term average of annual river water temperature from the NADUF dataset supports the assumption of significant in-stream productivity.…”

“…It has been argued that in-stream productivity of major lowland rivers, where flow velocities and suspended sediment concentrations diminish, are significant contributors of riverine organic carbon [33,83]. Moreover, Chen et al [83] recently suggested that even in mountainous rivers in-stream production and transformation of carbon exerts a significant influence on riverine DO 14 C dynamics. Riverine in-stream transformations can be separated into biotic (e.g.…”

“…However, compared with the low 14 C signatures emanating from upland regions of Swiss rivers, the magnitude of change in DOC 14 C values would instead correspond to higher 14 C values [79,81,82] given that Swiss riverine DOC generally exhibits relatively low 14 C values compared with the global average [28,32]. It has been argued that in-stream productivity of major lowland rivers, where flow velocities and suspended sediment concentrations diminish, are significant contributors of riverine organic carbon [33,83]. Moreover, Chen et al [83] recently suggested that even in mountainous rivers in-stream production and transformation of carbon exerts a significant influence on riverine DO 14 C dynamics.…”