The quaternary Rockeskyllerkopf Volcanic Complex (RVC) comprises three spatially and temporally distinct volcanic centers that can also be distinguished on the basis of their geochemical signatures. All the volcanic products in the complex are olivine basanites whose major and trace element compositions span almost the entire range defined for the West Eifel field as a whole. The RVC lavas have lower Al 2 O 3 , Na 2 O and Y contents and higher TiO 2 , CaO, K 2 O, Sc, V, Co, Rb, and Ba than the Tertiary lavas in nearby Hocheifel volcanic field. Within the complex, the oldest South East Lammersdorf Center (SEL) comprises primitive lavas with an average MgO content of ∼11 wt.% and La N /Yb N of 29±2. The second center, Mäuseberg, has similar MgO to SEL but is distinct in its much higher La N /Yb N of 42±2. The Rockeskyllerkopf Center, which was erupted after a break in activity, comprises lavas similar in composition to the SEL Center but with distinctly higher Al 2 O 3 and lower MgO contents. Given the lack of evidence for significant fractionation or assimilation in the RVC lavas, we attribute the compositional variations within and between the centers of the RVC to be due to variations in the composition of the source region in combination with magma mixing. Our preferred model involves 1-5% partial melting of LREE-enriched mantle in the garnet stability field, likely within the thermal boundary layer at the base of the lithospheric mantle. These melts mixed to variable degrees with 2-4% partial melts of phlogopite-spinel peridotite formed at higher levels in the modally metasomatised lithospheric mantle.