Geochronology, petrogenesis and metallogeny of Piaotang granitoids in the tungsten deposit region of South China

Abstract

The tungsten deposit region of South China is well known as the world's leading tungsten (W) producer. The Piaotang tungsten deposit in the region is such a representative large-scale quartz vein type tungsten polymetallic deposit that is closely associated with granitoids. In the present study we present precise LA-ICP-MS zircon U-Pb dating and LA-MC-ICPMS zircon Hf isotopic data for the samples from exposed quartz diorite body and buried granite stock in the Piaotang tungsten deposit area. Zircon U-Pb dating results indicate that the quartz diorite body was formed in Early Paleozoic time at 439 ± 2 Ma, whereas the granite body was emplaced in Early Yanshanian time at 158 ± 3 Ma. Both the quartz diorite and granite have negative ε Hf (t) values, with similar two-stage zircon Hf model ages ranging from 1.8 to 2.1 Ga. Through integration of our new data with the isotope data of Precambrian basement rocks in western Cathaysia, we suggest that the Paleoproterozoic Hf model ages (1.8-2.1 Ga) might be an average age which resulted from mixing of continental materials of different ages. Both the Piaotang Early Paleozoic quartz diorite and Early Yanshanian granite are produced by reworking of the heterogeneous Neoproterozoic crust. Our zircon ages, together with the geochemical data and geological features and ore-forming ages of this tungsten deposit, indicate that the buried Early Yanshanian granite, rather than the exposed quartz diorite, is genetically associated with tungsten mineralization.The distinct metallogeny difference between the Piaotang Early Paleozoic quartz diorite and Early Yanshanian granite can be ascribed to the different degrees of magma differentiation. The Early Yanshanian granite is highly differentiated rock and similar to the other W-Sn deposits generating granitoids in South China. The extents of magma differentiation depend on the tectonic setting and the mechanism of magma generation. On the basis of the relationship between two different stages of magmatism and W mineralization in the Piaotang tungsten deposit, and the similarities with other granite related W-Sn deposits in the same region, it is proposed that the regional tectonic setting and lithosphere dynamics are the key factors controlling the metallogenic capacity of granitoids in South China.

Zircon U–Pb geochronology, geochemical and Sr–Nd–Hf isotopic compositions of the Triassic granite and diorite dikes from the Wulonggou mining area in the Eastern Kunlun Orogen, NW China: Petrogenesis and tectonic implications

“…It is worth mentioning that the 10,000 Ga/Al ratios (1.28-1.72) are less than those of typical A-type granites (N2.6; Whalen et al, 1987), although high Ga/Al values appear to be particularly diagnostic of A-type granites (Whalen et al, 1987), perhaps because such A-type granites may have undergone simple rather than extensive fractional crystallization. If extensive fractional crystallization occurred, there would be higher levels of Ga in highly evolved granites (Eby, 1992;He et al, 2010). Alternatively, the low values may be generated because the Ga analyzed by ICP-MS was undervalued in this study, just as high quality Ga data are rare in the published literature (Whalen et al, 1987).…”

“…The data acquisition for each analysis took 100 s (40 s on background and 60 s on signal). The detailed analytical procedures of the LA-ICP-MS zircon U-Pb dating are described by Yang et al (2011) and He et al (2010).…”

Early Eocene sedimentary recycling in the Kailas area, southwestern Tibet: Implications for the initial India–Asia collision

“…Details of the instrumental conditions and data acquisition can be found in He et al (2010) and Xie et al (2008), respectively. Various spot diameters (25, 30, 44 μm) were used during the analysis depending on the grain size of zircon.…”

Episodic eruptions of the Late Mesozoic volcanic sequences in southeastern Zhejiang, SE China: Petrogenesis and implications for the geodynamics of paleo-Pacific subduction

“…The analytical details were similar to He et al (2010b). A 10 Hz repetition rate, beam diameter of 60 μm, and pulse energy density of 5.27-7.91 J/cm 2 were used.…”