Geochemistry of the Paleocene Clastic Rocks From the Southwestern Jianghan Basin, Central China Reveal Their Provenance, Tectonic Setting, and Palaeoenvironment

Abstract

This paper intends to learn about the provenance, tectonic setting and paleoenvironment of the Paleocene Shashi Formation in the southern Jianghan Basin by the bulk-rock geochemistry. The K2O/Al2O3 and SiO2/Al2O3 ratios indicate that the major proportion of samples are litharenite. The chondrite-normalized REE distribution pattern of the Shashi Formation’s mudstones are characterized by enriched LREE and flat HREE similar to those of UC with negative Eu anomalies. Combined with the geochemical element ratio discriminant diagram, such as Al2O3-TiO2, Zr-TiO2, La/Sc-Co/Th, and Hf-La/Th, so on, these samples were sourced from mixed felsic/basic rock. Moreover, the discriminant diagrams of K2O/Na2O-SiO2/Al2O3, La-Th-Sc, and Th-Co-Zr/10 suggest that the samples were formed under the tectonic settings of active continental margin and continental island arc. The values of CIA, CIW, PIA, ICV, Zr/Sc-Th/Sc, and ternary diagrams of A-(CN)-K and Al2O3-Zr-TiO2 indicate that weathering in the source area was weak and source rocks have not been reformed by depositional recirculation and hydraulic sorting. And the palaeoenvironmental indicators of C-value, Ni/Co, V/Cr, V/(V+Ni) and Sr/Cu, Ga/Rb indicate that the climate was cool and arid during the evaporite deposition period in the southern Jianghan Basin, and the water was in the condition of oxidation.