Geochemistry of low-temperature water–rock interaction: evidence from natural waters, andesite, and iron-oxyhydroxide precipitates at Nishiki-numa iron-spring, Hokkaido, Japan

Bau, Michael; Usui, Akira; Pracejus, Bernhard; Mita, Naoki; Kanai, Yutaka; Irber, Wolfgang; Dulski, Peter

doi:10.1016/s0009-2541(98)00086-2

Cited by 75 publications

(48 citation statements)

References 25 publications

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“…4 speciation, it cannot be used to comprehensively describe scavenging of elements with complex speciation, such as the REY, during formation of hydrogenetic Fe-Mn crusts. Obviously, the surface-complexation of dissolved REY with ligands (predominantly hydroxyl groups) at the oxide particle surfaces, which is significantly stronger for Ho than for Y (e.g., Byrne and Lee, 1993;Bau et al, , 1998Bau, 1999), promotes the preferential scavenging of Ho over Y and ultimately produces lower Y/Ho ratios in both Mn oxides and Fe oxides when compared to ambient seawater (remember that the anomalously weak surface-complexation of Y relative to Ho and its REE neighbours is the ultimate reason for the positive Y anomaly and super-chondritic Y/Ho ratio of seawater). However, the strong differences between the REY patterns of the Mn and the Fe oxides cannot be explained by REY solution-complexation alone, and hence, they suggest that REY fractionation during surface-complexation on hydrous Fe oxides differs from that on Mn oxides, supporting the findings of Quinn et al (2004) who argued that in contrast to Mn oxides, REY surface-complexation on Fe (hydr)oxides cannot be approximated by the first hydrolysis constants of the REY.…”

Section: Rey Fractionation Between Co-existing Mn Oxides and Hydrous mentioning

confidence: 99%

Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts

2009

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The distribution of the rare earths and yttrium (REY) in co-existing hydrous Mn oxides and Fe oxides that form marine hydrogenetic ferromanganese crusts is used to better describe the partitioning and fractionation of the REY between these (hydr)oxides and seawater in the natural marine system. Four fractions (easily exchangeable, Mn-oxide-bound, Fe-oxidebound, and insoluble-residue-bound REY) were separated by an adjusted sequential leaching procedure from two ferromanganese crusts from the Central Pacific. The distribution of the REY differs significantly between these leaching fractions and gives evidence for decoupling of La, Ce, Gd, Y, and Lu from their respective neighbours in the REY series during partitioning between hydrous Fe oxides, Mn oxides and seawater. Both the Mn oxides and the Fe oxides display pronounced positive Ce anomalies of almost similar size. This suggests that in the natural marine system oxidative scavenging of Ce from seawater is not restricted to Mn oxides but also occurs on hydrous Fe oxides. The distribution of Ce between the Mn oxides and the hydrous Fe oxides follows that of the trivalent REY and contrasts sharply with that of tetravalent Zr, Hf and Th. This suggests that preferential Ce removal from seawater does not result from the oxidation of dissolved Ce(III) within the marine water column, but that Ce(III) is oxidized after its sorption at the metal (hydr)oxide surface. Patterns of apparent hydrous Fe oxide/Mn oxide distribution coefficients show a sigmoidal shape and display negative anomalies for La, Gd, Y, and Lu (and the M-type lanthanide tetrad effect), indicating preferential scavenging of these elements by the Mn oxides as compared to the Fe oxides. The pronounced differences between the REY distribution in the Mn oxides and that in the Fe oxides cannot solely be explained by the REY speciation in seawater, but require additional and mineral-specific REY fractionation during surface-complexation.

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Section: Rey Fractionation Between Co-existing Mn Oxides and Hydrous mentioning

confidence: 99%

Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts

2009

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“…The leaching or enrichment of elements depends on various environmental conditions (Karakaya et al 2007). Bau et al (1998) determined the following order of mobility in spring waters: Gislason et al (1996), in a study of rivers in Iceland, observed a trend of Na…”

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confidence: 99%

Effect of Alteration Zones on Water Quality: A Case Study from Biga Peninsula, Turkey

Baba

Gündüz

2009

Arch Environ Contam Toxicol

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Widespread and intense zones of silicified, propylitic, and argillic alteration can be found in the Ç an volcanics of Biga Peninsula, northwest Turkey. Most of the springs in the study area surface out from the boundary between fractured aquifer (silicified zone) and impervious boundary (argillic zone). This study focuses on two such springs in Kirazlı area (Kirazlı and Balaban springs) with a distinct quality pattern. Accordingly, field parameters (temperature, pH, and electrical conductivity), major anion and cation (sodium, potassium, calcium, magnesium, chloride, bicarbonate, and sulfate), heavy metals (aluminum, arsenic, barium, chromium, cobalt, cupper, iron, lithium, manganese, nickel, lead, and zinc), and isotopes (oxygen-18, deuterium, and tritium) were determined in water samples taken from these springs during 2005 through 2007. The chemical analyses showed that aluminum concentrations were found to be two orders of magnitude greater in Kirazlı waters (mean value 13813.25 lg/L). The levels of this element exceeded the maximum allowable limits given in national and international standards for drinking-water quality. In addition, Balaban and Kirazlı springs are [55 years old according to their tritium levels; Kirazlı spring is older than Balaban spring. Kirazlı spring is also more enriched than Balaban spring based in oxygen-18 and deuterium values. Furthermore, Kirazlı spring water has been in contact with altered rocks longer than Balaban spring water, according to its relatively high chloride and electrical conductivity values.Water-rock interaction is an important topic influencing the water quality as well as human health. Particularly in altered systems, these interactions are more important for local inhabitants using water for drinking purposes because the water in such systems might contain increased levels of certain elements that are potentially detrimental to human health. Thus, these interactions should be assessed carefully in areas of complex geology where rocks formed as a result of hydrothermal system are predominant.Hydrothermal fluids carry metals in solution, coming either from a nearby igneous source, from leaching of subsurface rocks, or both (Henley et al. 1984). These fluids then alter other rocks, changing their mineralogy and chemical composition (Nicholson 1993;Verma et al. 2005;Pandarinath et al. 2008). Complex zoned alteration patterns have been well documented from a large number of important hydrothermal ore deposit types, including submarine-volcanogenic massive sulphide (Finlow-Bates and

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“…Results from leaching experiments are generally reported for pure water (e.g., Mö ller and Giese, 1997;Bach and Irber, 1998;Bau et al, 1998), and adsorption processes are investigated in a solution of known composition (Coppin et al, 2002;Takahashi et al, 2004). In order to compare the results obtained from our leaching experiment with literature data, we favoured the use of a trace-element-free seawater.…”

mentioning

confidence: 89%

“…These were calculated according Bau et al (1998) for the investigated trace elements, and are given in Table 4. The YREE release from newly-formed volcanic ash under the experimental conditions discussed in Section 2.4 is well-described by a first order kinetic model.…”

Section: Kinetic Experimentsmentioning

confidence: 99%

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Alteration effects of volcanic ash in seawater: Anomalous Y/Ho ratios in coastal waters of the Central Mediterranean sea

Censi

Sprovieri

Larocca

et al. 2007

Geochimica et Cosmochimica Acta

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This paper presents the results of a study based on data collected during the oceanographic cruise ANSIC 2001 carried out in the Ionian Sea during the explosive activity of Mount Etna in the summer of 2001. Anomalous low values of Y/Ho ratios in seawater suggest extensive scavenging processes on the surfaces of smectitic alteration products, with Y and Ho fractionation controlled by the differences in their electronic configurations and behaviour during solution/surface complexation equilibria. These processes can also be traced through the presence of significant tetrad effects recorded in the chondrite-normalised Rare Earth Elements and Yttrium (YREEs) patterns of suspended particulate matter. This suggests that the preferential Y scavenging from seawater is due to the formation of inner-sphere complexes with OH À groups on montmorillonite crystal surfaces. The preliminary results of kinetic experiments of YREE released from volcanic ash to coexisting seawater, and the related effects on Y/Ho ratios and Ce anomalies, are consistent with the fractionation of Light Rare Earth Elements (LREEs) with respect to Heavy Rare Earth Elements (HREEs) observed in dissolved phase. They suggest a behaviour of Y similar to that reported for LREEs, particularly for Ce and Pr.

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Geochemistry of low-temperature water–rock interaction: evidence from natural waters, andesite, and iron-oxyhydroxide precipitates at Nishiki-numa iron-spring, Hokkaido, Japan

Cited by 75 publications

References 25 publications

Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts

Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts

Effect of Alteration Zones on Water Quality: A Case Study from Biga Peninsula, Turkey

Alteration effects of volcanic ash in seawater: Anomalous Y/Ho ratios in coastal waters of the Central Mediterranean sea

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