2006
DOI: 10.1007/s10582-006-0491-x
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Geochemical study of uranium mobility in tertiary argillaceous system at Ruprechtov site, Czech Republic

Abstract: The natural analogue study at the Ruprechtov site is aimed to investigate and understand the behaviour of natural radioelements in plastic clay formation. Uranium is present predominantly in U(+IV) form, either in secondary uranium minerals (uraninite, ningyoite) or in detrital immobile phases (monazite, rhabdophane, xenotime, zircon) and in hardly characterisable non-crystalline forms as well. Process of uranium accumulation probably proceeded via reduction of U(VI) and U(IV) precipitation with involvement of… Show more

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Cited by 3 publications
(2 citation statements)
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“…For uranium, uraninite (UO 2 ) was assumed to be the solubility-controlling phase because of its presence in the waste form. This treatment is consistent with a natural analogue study of uranium fixation in a Tertiary argillite (Havlova et al 2006).…”
Section: Radionuclide Dispersionsupporting
confidence: 87%
“…For uranium, uraninite (UO 2 ) was assumed to be the solubility-controlling phase because of its presence in the waste form. This treatment is consistent with a natural analogue study of uranium fixation in a Tertiary argillite (Havlova et al 2006).…”
Section: Radionuclide Dispersionsupporting
confidence: 87%
“…The sequential extraction method, which is a classical approach that enables to determine trace metal forms in sedimentary rocks, was used in a slightly modified and reduced scheme with the aim to obtain the information about the uranium amount that is attainable from the rock in contact with the underground water composition which is characteristic for the site (Havlová et al 2006). …”
Section: Sequential Extraction and Isotope Exchange Using 233 Umentioning
confidence: 99%