Evaporite salts from
saline lakes and playas play active
roles
in the atmospheric cycles and the climate system, especially in the
context of changing climate. This study investigates the chemical,
isotopic, and hygroscopic characteristics of surface salt samples
from two saline lakes, i.e., Mang’ai and Dalangtan (MA and
DLT), in the Qaidam Basin. Samples from both lakes shared similar
ionic compositions, with brines rich in Cl–, Mg2+, and Na+, and lakebed salts being primarily NaCl-based.
Disparities in the composition between MA and DLT crust salts were
observed. Isotopic analyses revealed consistent δ34S values within samples from a single site, hinting at a common origin.
The sulfur source for the MA saline lake likely arises from nearby
freshwater inflows and atmospheric deposits. The δ37Cl values varied by sample type, with solid samples typically exhibiting
higher values than brines, attributed to 37Cl depletion
during precipitation. Ionic composition largely determines hygroscopic
properties. While brines started moisture absorption around 40% relative
humidity (RH), lakebed salts commenced at 70% RH. The DLT playa salt,
enriched in Na2SO4, demonstrated a unique behavior,
responding significantly only above 80% RH. The layered DLT samples
showcased variable hygroscopic behaviors, particularly the early moisture
uptake of the topmost layer, despite its ionic similarity to another
layer, hinting at molecular or hydration disparities. In conclusion,
this investigation unravels the multifaceted relationship between
salt evaporites composition and their implications for atmospheric
chemistry.