“…Underground fluid is proved to be an important carrier for transmitting information of geological evolution within the Earth and thus its geochemical characteristics and genesis are widely studied (Zhang, 1992;Che et al, 1998;Du and Kang, 2000;Liu, 2006;Li et al, 2022;. Detailed researches involving the relationship between groundwater and surface runoff (Grasby et al, 1999;Su et al, 2009;Gu et al, 2017), the circulation process and waterrock interactions (He and Singh, 2019;Hosono and Masaki, 2020;Hosono et al, 2019;Nakagawa et al, 2020;Shi et al, 2020;Barberio et al, 2017;Skelton et al, 2014;Barberioet al, 2017;Zhou et al, 2020;Chen et al, 2015;Li et al, 2021;Martinelli and Dadomo, 2017;Skelton et al, 2019;Li et al, 2017;Bao et al, 2019;Du and Liu, 2003;Sun et al, 2016;Zhou et al, 2022;Tian et al, 2021;Song et al, 2006), the changes of chemical compositions before and after earthquakes (Tsunogai and Wakita, 1995;Claesson et al, 2004;He and Singh, 2019;Hosono and Masaki, 2020;Hosono et al, 2019;Nakagawa et al, 2020;Shi et al, 2020;Barberio et al, 2017;Skelton et al, 2014;Barberioet al, 2017;Zhou et al, 2020;…”