2015
DOI: 10.1016/j.catena.2015.07.003
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Geochemical background in polluted river sediments: How to separate the effects of sediment provenance and grain size with statistical rigour?

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Cited by 92 publications
(43 citation statements)
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“…In particular, the Al/Si ratio is used as a proxy for particle size in sediment provenance research ( Figure 9) (Bouchez et al, 2011). Other ratios may indeed be effective, such as the Ca/Al ratio (Chen et al, 2014), along with particle size sensitive elements such as Ti (Bábek et al, 2015), or even simply clay content (Szava-Kovats, 2008). For example, studies reconstructing the evolution of metal enrichment ratios in sediment have also normalized elemental concentrations to Sc, Al, Si, Li or Th to minimize particle size impacts when examining contamination trends (Ayrault et al, 2010;Clark et al, 2014;Grosbois et al, 2012;Kersten and Smedes, 2002;Le Cloarec et al, 2011).…”
Section: Elemental Ratios and Elemental Normalisationmentioning
confidence: 99%
See 1 more Smart Citation
“…In particular, the Al/Si ratio is used as a proxy for particle size in sediment provenance research ( Figure 9) (Bouchez et al, 2011). Other ratios may indeed be effective, such as the Ca/Al ratio (Chen et al, 2014), along with particle size sensitive elements such as Ti (Bábek et al, 2015), or even simply clay content (Szava-Kovats, 2008). For example, studies reconstructing the evolution of metal enrichment ratios in sediment have also normalized elemental concentrations to Sc, Al, Si, Li or Th to minimize particle size impacts when examining contamination trends (Ayrault et al, 2010;Clark et al, 2014;Grosbois et al, 2012;Kersten and Smedes, 2002;Le Cloarec et al, 2011).…”
Section: Elemental Ratios and Elemental Normalisationmentioning
confidence: 99%
“…For example, studies reconstructing the evolution of metal enrichment ratios in sediment have also normalized elemental concentrations to Sc, Al, Si, Li or Th to minimize particle size impacts when examining contamination trends (Ayrault et al, 2010;Clark et al, 2014;Grosbois et al, 2012;Kersten and Smedes, 2002;Le Cloarec et al, 2011). Indeed, there are multiple approaches from the sediment provenance field (Armstrong-Altrin et al, 2015;Bábek et al, 2015;Owens et al, 2016;Singh et al, 2005) that present significant opportunities for enhancing the sediment source fingerprinting technique (e.g. Vale et al, 2016).…”
Section: Elemental Ratios and Elemental Normalisationmentioning
confidence: 99%
“…Most chemical elements (both polluting and lithogenic) in chemically mature sediments are grain-size sensitive. For example, the aluminium to silicon (Al/Si) ratio is considered a "surrogate" for grain size of fluvial sediments [45][46][47], because, in mature sediments, this ratio increases with a growing percentage of clay fraction (usually dominated by aluminosilicate clay minerals) at the expense of sand (usually dominated by quartz). Conversely, the zirconium to rubidium (Zr/Rb) ratio in sediments is proportional to coarser particle content, in particular coarse silt and the finest sand [48,49], because Zr is mainly carried by zircon crystals with a typical grain size of 0.05 to 0.1 mm, and because in mature sediments, Rb occurs mainly in finer clay mineral particles.…”
Section: Pollution Mappingmentioning
confidence: 99%
“…This may cause sedimentation. Sediment sourced from estuaries and rivers will take place triggering the higher suspended sediment concentration in water (Bábek et al, 2015).…”
Section: Introductionmentioning
confidence: 99%