The Wadi Al-Qassab and Wadi Al-Murr are the main valleys in the west of the town of Qaiyarah, extending almost parallel in the northwest-southeast direction and descending from the topographically high areas located to the west towards the Tigris River in the east. Wadi Al-Qassab extends in the area sandwiched between the mountains (Attshan, Nuegett and Eklayan) in the north of the valley and the mountains (Jawan, Najmah and Qaiyarah) south of the valley which represents anticlines. While Wadi Al-Murr extends to the south of the mountains (Najmah and Qaiyarah). These two valleys are active during the rainy season due to the wide catchment area, especially for Wadi Al-Qassab, which several seasonal tributaries flow. The structural situation reflected by the Qaiyarah and Najma anticlines helps reveal many types of rocks belonging to the Fat'ha and Injana formations, as well as the sediments that cover the area mainly derived from the rocks of these two formations. The two valleys' sediments were classified as sand and gravelly sand that will contribute to the groundwater recharge during the rainy season. The average mineral compositions of the sediments (according to X-ray data and chemical composition of major and minor oxides) in the valleys of Al-Murr and Al-Qassab were estimated to be silicate minerals (such as quartz, clay minerals and feldspar minerals) estimated at 62.78% and 59.89%, carbonate minerals (main calcite) 26.14% and 31.97%, the evaporite minerals that included gypsum mineral 5.46% and 2.87% and halite 0.62% and 0.36%, in addition to the iron oxide phases of 4.69% and 4.41%, respectively. Most of the trace elements have been associated with clay minerals, either in the form of substitution and/or adsorption, and some of them are maybe as resistant minerals inherited from the source rocks from which they were derived. Chemical analysis shows that there are no significant indicators of hydrocarbon pollutions that may enrich the area with some organometallic compounds in valley sediments due to the emitted refinery gases and fine hydrocarbon particles.