Abstract:Nucleophilic mixed chromium(II) and chromium(III) acetylides are generated from the smooth reduction of primary 1,1,1-trichloroalkanes with chromium(II) chloride in the presence of an excess amount of triethylamine at room temperature. These species arise from chromium(III) vinylidene carbenoids. It has been demonstrated that uncommon low-valent CrII acetylides are formed by C–H insertion of CrIICl2 into terminal alkynes, formed in situ through the Fritsch– Buttenberg–Wiechell (FBW) rearrangement, whereas CrII… Show more
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