Two types of glass fiber reinforced plastic (GFRP) composites were fabricated viz., GFRP with neat epoxy matrix (GFRP-neat) and GFRP with hybrid modified epoxy matrix (GFRP-hybrid) containing 9 wt. % of rubber microparticles and 10 wt. % of silica nanoparticles. Fatigue tests were conducted on both the composites under the WISPERX load sequence. The fatigue life of the GFRP-hybrid composite was about 4-5 times higher than that of the GFRP-neat composite. The underlying mechanisms for improved fatigue performance are discussed. A reasonably good correlation was observed between the experimental fatigue life and the fatigue life predicted under the spectrum loads.Keywords: glass fiber composite, silica nanoparticle, rubber particle, spectrum fatigue. * Corresponding author: Tel. +91-80-2508 6310; Fax: +91-80-2508 6301 E-mail address: manjucm@nal.res.in (CM Manjunatha) 2
INTRODUCTIONDue mainly to their high specific strength and stiffness, continuous fiber reinforced plastic (FRP) composites are widely used in various structural applications such as airframes, wind turbines, ship hulls, etc. Such composite structural components experience variable amplitude or spectrum fatigue loads in service. Hence, the fatiguedurability of the composite materials under spectrum loads is an important requirement in these applications.Engineering polymer matrix composite materials generally consist of continuous glass or carbon fibers embedded in a thermosetting epoxy polymer. The epoxy polymer, being an amorphous and highly cross-linked material, is relatively brittle and exhibits a relatively poor resistance to crack initiation and growth, thus affecting the overall mechanical properties, including the fatigue and fracture behavior of FRP composites.One of the ways to improve the mechanical properties of FRPs is to add a second phase of fillers into the epoxy matrix.Incorporation of various types of micro-and nano-sized spherical, fibrous and layered fillers into the epoxy has been shown to improve the mechanical properties of composites [1][2][3]. Considerable improvements in the strength and stiffness [4], and dramatic improvements in the fracture toughness [3][4][5]
EXPERIMENTAL
Materials and ProcessingThe materials used and the processing employed to manufacture GFRP composites are briefly explained in this section. However, a detailed description of the materials and processing can be found in [24]. The epoxy resin used was LY556 from Huntsman, which is a diglycidyl ether of bisphenol A (DGEBA) resin. The silica (SiO 2 )nanoparticles were obtained as a colloidal silica sol with a concentration of 40 wt.% in LY556 from Nanoresins. The reactive liquid rubber was a carboxyl-terminated butadiene-acrylonitrile (CTBN) rubber, obtained from Nanoresins as a 40 wt.% CTBN-LY556 epoxy adduct. The curing agent was an accelerated methylhexahydrophthalic acid anhydride, HE600 from Nanoresins. The E-glass fiber cloth was a non-crimp-fabric (NCF) with an areal weight of 450 g/m 2 .The required quantity of the neat epoxy resin, th...