2008
DOI: 10.1007/s11144-008-5258-x
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Gas-phase toluene oxidation over platinum-containing mixed oxides

Abstract: The gas-phase toluene oxidation was studied over platinum-containing mixed oxides derived from hydrotalcite-like compounds with high specific surface area. Both the temperature of the reaction and toluene and oxygen initial concentrations proved to influence toluene oxidation rate. Activation energy of 107 and 248 kJ/mol was found for toluene and oxygen, respectively, with an oxygen dissociative model.

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Cited by 4 publications
(1 citation statement)
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“…At the same time, oxygen vacancies are generated on the catalyst surface and reduced, causing metal oxides in the catalyst to be reduced as well. In the second step, the reduced metal oxide in the catalyst is oxidized again by external O 2 to fill the oxygen vacancy in order to continue the first step reaction ( Rodrigues, 2008 )…”
Section: Introductionmentioning
confidence: 99%
“…At the same time, oxygen vacancies are generated on the catalyst surface and reduced, causing metal oxides in the catalyst to be reduced as well. In the second step, the reduced metal oxide in the catalyst is oxidized again by external O 2 to fill the oxygen vacancy in order to continue the first step reaction ( Rodrigues, 2008 )…”
Section: Introductionmentioning
confidence: 99%