Gas phase structure of ((fluoroformyl)imido)sulfuryl difluoride, FC(O)NS(O)F2

Structure and Conformational Properties of N-Pentafluorosulfur(sulfuroxide difluoride imide) SF5NS(O)F2: Vibrational Analysis, Gas Electron Diffraction, and Quantum Chemical Calculations

“…Furthermore, both N−C bonds in NN ‘-carbonyl-bis(sulfuroxidedifluoride imide, OC(NS(O)F 2 ) 2 , are oriented syn relative to the bisector of the SF 2 group . In a recent conformational study for N -fluoroformyl(sulfuroxidedifluoride imide), FC(O)NS(O)F 2 , however, a small amount of 14(8)% of a conformer with anticlinal orientation around the NS bond was observed . This study was complicated by the presence of one or two more conformers with different orientation of the FC(O) group around the N−C bond.…”

“…11 In a recent conformational study for N-fluoroformyl(sulfuroxidedifluoride imide), FC(O)NdS(O)F 2 , however, a small amount of 14(8)% of a conformer with anticlinal orientation around the NdS bond was observed. 12 This study was complicated by the presence of one or two more conformers with different orientation of the FC(O) group around the N-C bond. In the course of structural and conformational investigations of sulfur imide and sulfuroxide imide compounds we now report the results for Npentafluorosulfur(sulfuroxide difluoride imide), SF 5 NdS(O)-F 2 , as derived by vibrational spectroscopy, GED, and quantum chemical calculations.…”