Abstract:The absolute rate coefficient for the gas phase reaction of OH radical with 2-chloroethyl vinyl ether (H 2 C = CH-O-CH 2 CH 2 Cl, 2ClEVE) has been measured using the laser photolysis (LP)laser induced fluorescence (LIF) technique. The kinetics measurements were done over the temperature range of 256-333 K. The bimolecular rate coefficients obtained, k(T), showed Arrhenius type behaviour which were fitted to the expression k(T) = (4.18 AE 0.55) 3 10 À12 exp[(700 AE 70)/T] cm 3 molecule À1 s À1 .The room tempera… Show more
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