“…This 2D nature of the SnS layer renders only aw eak interaction between neighboring layers via van der Waalsi nteractions, which allows easy separation andfabrication of layered composite structures with highly disparate atomic layerst oc reate aw ide range of van der Waals( vdWs)h eterostructures without any constraints of lattice match and compatibility.T herefore, the processability of SnS combined with its extraordinary physicala nd chemical properties makes it ap erfect model system in exploring new 2D properties. [2][3][4][5][6] Recently,s cattered layerso fS nS on either mica or Si wafer, prepared fromc ommercialS nS powers via av apor phase transportm ethod, have been successfully used in variousa pplications such as the field effect transistors, [14,15] anisotropic field-effect transistors, [5] solid-ionb atteries (chemically derived SnS), [16] near-infraredp hotodetectors, [17] gas dependentp hotodetectors, [18] and anisotropic core-shell photoactive heterostructures. [19] Such diverse applicationso fS nS layers reflect the inherentf unctional richness of the SnS layers such as 2D anisotropic optical, electrical and thermoelectric properties of SnS [5,6,10,20] as has been experimentally determinedf rom the thickness, angle, and temperature-dependent Raman characteristics.…”