2009
DOI: 10.1007/s10450-009-9150-4
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Gas adsorption process in activated carbon over a wide temperature range above the critical point. Part 2: conservation of mass and energy

Abstract: Simulations of the thermal effects during adsorption cycles are a valuable tool for the design of efficient adsorption-based systems such as gas storage, gas separation and adsorption-based heat pumps. In this paper, we present simulations of the thermal phenomena associated with hydrogen, nitrogen and methane adsorption on activated carbon for supercritical temperatures and high pressures. The analytical expressions of adsorption and of the internal energy of the adsorbed phase are calculated from a DubininAs… Show more

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Cited by 54 publications
(56 citation statements)
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“…These are developed in a prior work by Richard et al and used in this study. 4 Following conditions are used in the thermal simulations:…”
Section: Thermal Effects In the Adsorption System Simulation Of Thermmentioning
confidence: 99%
See 1 more Smart Citation
“…These are developed in a prior work by Richard et al and used in this study. 4 Following conditions are used in the thermal simulations:…”
Section: Thermal Effects In the Adsorption System Simulation Of Thermmentioning
confidence: 99%
“…3,4 This modification allowed a threefold reduction of the standard error of fitting experimental adsorption data of the H 2 /AX-21 TM system over a wide temperature and pressure range in the supercritical region. It also made it possible to fit the model's parameters using only two isotherms measured at 77 K and 298 K without significantly reducing the quality of the fit over the whole ).…”
mentioning
confidence: 99%
“…But in this study only one overall energy balance was utilised by combining the two energy balances in the gas and stationary phases under an assumption that the adsorbent, adsorbed gas and gas phases are at their thermal equilibrium in the control volume (Mahle et al 1996;Richard et al 2009).…”
Section: Introductionmentioning
confidence: 99%
“…The heat of adsorption cannot be neglected. Its value depends on temperature and surface loading, for interesting pressure range of can be estimated according to [4] as a range 12 -20 kJ/mol The isotherms showed in FIGURE 2 are a compilation of data published in [5] and the experiments performed in National University of Singapore. The observed temperature dependent shape is an indication of possible pressure benefit for different filling temperatures.…”
Section: Adsorbed Natural Gas and Comparison With Other Gas Storage Mmentioning
confidence: 99%