Gamma-induced interconnected networks in microporous activated carbons from palm petiole under NaNO3 oxidizing environment towards high-performance electric double layer capacitors (EDLCs)

Abstract

Activated carbons (ACs) were developed from palm petiole via a new eco-friendly method composed of highly diluted H2SO4 hydrothermal carbonization and low-concentration KOH-activating pyrolysis followed by gamma-induced surface modification under NaNO3 oxidizing environment. The prepared graphitic carbons were subsequently used as an active material for supercapacitor electrodes. The physiochemical properties of the ACs were characterized using field emission scanning electron microscope–energy dispersive X-ray spectroscopy, N2 adsorption/desorption isotherms with Brunauer–Emmett–Teller surface area analysis, Fourier transform infrared spectroscopy, X-ray diffraction and Raman spectroscopy. The electrochemical performance of the fabricated electrodes was investigated by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy. Even treated with extremely low H2SO4 concentration and small KOH:hydrochar ratio, the maximum SBET of 1365 m2 g−1 for an AC was obtained after gamma irradiation. This was attributed to radiation-induced interconnected network formation generating micropores within the material structure. The supercapacitor electrodes exhibited electric double-layer capacitance giving the highest specific capacitance of 309 F g−1 as well as excellent cycle stability within 10,000 cycles. The promising results strongly ensure high possibility of the eco-friendly method application in supercapacitor material production.

Hierarchical Porous Carbon Aerogel Derived from Sodium Alginate for High Performance Electrochemical Capacitor Electrode

“…However, poor cycle stability and rate capability contribute to the failure of commercialization so far. Therefore, a number of recent research efforts still focus on various carbon materials [5,6]. Moreover, the porous carbon with hierarchical pores (i.e., macropores, mesopores, and micropores) is ideal candidate for electrochemical capacitor.…”