One of the principal mechanisms that is responsible for the origin of blue
stragglers is mass transfer that takes place while one of the binary companions
overfills its Roche lobe. In this Chapter, we overview the theoretical
understanding of mass transfer via Roche lobe overflow: classification, how
both the donor and of the accretor respond to the mass transfer on different
timescales (adiabatic response, equilibrium response, superadiabatic response,
time-dependent response) for different types of their envelopes (convective and
radiative). These responses, as well as the assumption on how liberal the
process is, are discussed in terms of the stability of the ensuing mass
transfer. The predictions of the theory of mass transfer via Roche lobe
overflow are then briefly compared with the observed mass-transferring systems
with both degenerate and non-degenerate donors. We conclude with the discussion
which cases of mass transfer and which primordial binaries could be responsible
for blue stragglers formation via Roche lobe overflow, as well as how this can
be enhanced for blue stragglers formed in globular clusters.Comment: Chapter 8, in Ecology of Blue Straggler Stars, H.M.J. Boffin, G.
Carraro & G. Beccari (Eds), Astrophysics and Space Science Library, Springe