Heavily Sidoped GaAs grown by metalorganic chemical vapor depositionThe crystallinity of GaAs grown on Si with various intermediate layers by metalorganic chemical vapor deposition and characteristics of Schottky diodes fabricated on the grown GaAs/Si have been studied. The GaAs/Si with an Alo.5sGa0.4SP intermediate layer has both good crystallinity, x-ray full width at half maximum of 188 arcsec, and a smooth surface. The Schottky diode fabricated on the GaAs/Si with an Alo.55Gao.4SP intermediate layer also shows good forward and reverse current-voltage characteristics with an ideality factor of 1.06, as good as for an n-type GaAs substrate. However, a relatively large leakage current is observed under reverse and small forward bias. This leakage current is caused by generation and recombination through the centers related to dislocations in the GaAs/Si.