Future green chemistry and sustainability needs in polymeric coatings

Cunningham, Michael F.; Campbell, J. D.; Fu, Zhenwen; Bohling, James C.; Leroux, Jacques; Mabee, Warren; Robert, Tobias

doi:10.1039/c9gc02462j

Cited by 66 publications

(43 citation statements)

References 46 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The growing interest in bio‐derived NIPUs and the commitment of the coating industry to improve their sustainability makes terpene‐derived cyclic carbonates desired compounds. 1,2,8,9‐Limonene biscarbonate has previously been used in NIPU synthesis to show promising results .…”

Section: Discussionmentioning

confidence: 99%

Selective Catalytic Synthesis of 1,2‐ and 8,9‐Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes

Maltby

Hutchby

Pluciński

et al. 2020

Chemistry A European J

View full text Add to dashboard Cite

The selective catalytic synthesis of limonene‐derived monofunctional cyclic carbonates and their subsequent functionalisation via thiol–ene addition and amine ring‐opening is reported. A phosphotungstate polyoxometalate catalyst used for limonene epoxidation in the 1,2‐position is shown to also be active in cyclic carbonate synthesis, allowing a two‐step, one‐pot synthesis without intermittent epoxide isolation. When used in conjunction with a classical halide catalyst, the polyoxometalate increased the rate of carbonation in a synergistic double‐activation of both substrates. The cis isomer is shown to be responsible for incomplete conversion and by‐product formation in commercial mixtures of 1,2‐limomene oxide. Carbonation of 8,9‐limonene epoxide furnished the 8,9‐limonene carbonate for the first time. Both cyclic carbonates underwent thiol–ene addition reactions to yield linked di‐monocarbonates, which can be used in linear non‐isocyanate polyurethanes synthesis, as shown by their facile ring‐opening with N‐hexylamine. Thus, the selective catalytic route to monofunctional limonene carbonates gives straightforward access to monomers for novel bio‐based polymers.

show abstract

Section: Discussionmentioning

confidence: 99%

Selective Catalytic Synthesis of 1,2‐ and 8,9‐Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes

Maltby

Hutchby

Pluciński

et al. 2020

Chemistry A European J

View full text Add to dashboard Cite

show abstract

“…[11][12][13] Further advantages of combining CRP techniques with emulsion polymerization to produce industrially relevant (block)copolymers are obvious: Waterborne processes are not only cheap, they moreover provide efficient heat transfer, a low viscosity, and renounce volatile organic compounds, while coincidently giving rise to well-defined polymer architectures. [14][15][16] Several methods based on the RDRP mechanism have been developed, the most common ones being the atom transfer radical polymerization (ATRP), 17,18 nitroxide-mediated polymerization (NMP), 19 and RAFT polymerization. 20,21 Besides the conventional thermal initiation, these methods allow control through external physical (light irradiation, ultrasonication) [22][23][24][25] and chemical stimuli (metal-, redox-, enzyme-, Lewis acid-, or electrochemicallycatalyzed), [26][27][28][29][30] with light being lately one of the most prominent initiation sources.…”

Section: Introductionmentioning

confidence: 99%

An eco-friendly pathway to thermosensitive micellar nanoobjects via photoRAFT PISA: the full guide to poly(N-acryloylpyrrolidin)-block-polystyrene diblock copolymers

Lauterbach

Abetz

2020

Soft Matter

View full text Add to dashboard Cite

show abstract

“…Industrial coatings play a key role in modern society, contributing significantly to our care, health and wellbeing. The protection provides by sealants, paints and other coatings preserves and extends the lifetime of buildings, transportation vehicles, industrial equipment and other infrastructure [152]. Many of the actual coatings for corrosion protection represent a threat to the environment.…”

Section: Industrial Coatingsmentioning

confidence: 99%

Nanostructured Surface Finishing and Coatings: Functional Properties and Applications

Ielo

Giacobello

Sfameni

et al. 2021

Preprint

View full text Add to dashboard Cite

This review presents current literature on different nanocomposites coatings and surface finishing for different substrates (such as textiles, concrete, plastics, stones, metals and so on). In particular, this study is focused on smart materials, drug delivery systems, and industrial, antifouling and nano/ultrafiltration membrane coatings. Each of these nanostructured coatings shows interesting properties for different fields of application. In this review, particular attention is paid to the synthesis and the consequent physico-chemical characteristics of each coating and, therefore, to the different parameters that influence the substrate deposition process. Several techniques used in the characterization of these surface finishing coatings are also described. In this review, the sol-gel and polymerization method for preparing stimuli-responsive coatings as smart sensor materials is described; functional polymers and nanoparticles sensitive to pH, temperature, phase, light and biomolecules are also treated. Finally, nanomaterials based on phosphorus, borates, hydroxy carbonates and silicones are used and described as flame retardant coatings; organic/inorganic hybrid sol-gel coatings for industrial applications are illustrated, together with functional nanofiller (carbon nanotubes, metallic oxides, etc.) and polymers employed for nano/ultrafiltration membrane and antifouling coatings. In the last decades, several research institutes and industries have collaborated for the advancement of nanotechnology by optimizing conversion processes of conventional materials into coatings with new functionalities for intelligent, innovative, eco-sustainable and advanced applications.

show abstract

Future green chemistry and sustainability needs in polymeric coatings

Abstract: Challenges and opportunities for paints and coatings.

Cited by 66 publications

References 46 publications

Selective Catalytic Synthesis of 1,2‐ and 8,9‐Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes

Selective Catalytic Synthesis of 1,2‐ and 8,9‐Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes

An eco-friendly pathway to thermosensitive micellar nanoobjects via photoRAFT PISA: the full guide to poly(N-acryloylpyrrolidin)-block-polystyrene diblock copolymers

Nanostructured Surface Finishing and Coatings: Functional Properties and Applications

Contact Info

Product

Resources

About