2023
DOI: 10.1039/d3cc03084a
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Fused metallacyclopropenes from alkynylphenols

Bingjie Fu,
Wei Bai,
Yue Zhao
et al.

Abstract: Metallabenzofuran-fused osmacyclopropene complexes are obtained from the reactions of OsCl2(PPh3)3 with 2-alkynylphenols. Paramagnetic alkyne-coordinated phenolate Os complexes are proposed to be the key intermediates.

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