Cd 1ÿ x Zn x Te (CZT) crystals grown from a modified vertical Bridgman technique were characterized by means of an optical polarized transmission technique using the Pockels effect, low-temperature direct current (DC) photoconductivity technique, low-temperature photoluminescence (PL) spectroscopy, room-temperature PL mapping technique, and detector performance measurements. Electric field mapping indicates that an approximation of a uniform electric field distribution approximation is generally satisfied for CZT detectors operated at room temperature under typical working conditions. A nonuniform electric field distribution is observed under intense infrared (IR) light illumination, and a model is proposed based on charge generation of defects, trapping, and space-charge effects. The largest hole mobility-lifetime product (mt) h of the CZT detector measured by DC photoconductivity is 7.0 3 10 ÿ 4 cm 2 /V. The detector treated with 2% bromine in methanol chemical etch has a relatively small surface recombination velocity at room temperature, which was obtained from DC photocurrent and detector performance tests, as measured by irradiation of 5.5-MeV a particles and 59.6-keV g-rays, respectively. We have clearly shown the equivalence of charge collection efficiency results measured by both DC photocurrent and a particle response. Lowtemperature DC photocurrent measurements show that surface recombination velocity increases significantly with decreasing temperature from 300 K to 250 K. The effective electron mobility-lifetime product-combination effects of bulk and surface of CZT crystal-increases with increment of temperature. Room-temperature PL mapping measurements indicate uniformity of zinc concentration within CZT crystals. Low-temperature PL spectroscopy shows that the dominant emission peaks are excitons, which are bound to either shallow neutral donors (D 0 , X) or neutral acceptors (A 0 , X), depending on the temperature, concentration of donors and acceptors, and the incident light intensity. It was found that the luminescence of (D 0 , X) depends linearly on the incident laser intensity, while (A 0 , X) has a nonlinear dependence.