Furfural oxidation to maleic acid with H2O2 by using vanadyl pyrophosphate and zirconium pyrophosphate supported on well-ordered mesoporous KIT-6

Rezaei, Masoume; Chermahini, Alireza Najafi; Dabbagh, Hossein A.; Saraji, Mohammad; Shahvar, Ali

doi:10.1016/j.jece.2018.102855

Cited by 32 publications

(18 citation statements)

References 38 publications

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“…Unlike the TS-1 catalyst, which mainly gave maleic acid as the product, in using robust sulfated zirconia as the catalyst for furfural oxidation with H 2 O 2 , Murzin found that the products were not so selective, resulting in the formation of a broad range of oxidation products including succinic acid, maleic acid, 2-(5 H )-furanone, and 5-hydroxy-2-(5 H )-furanone . In addition, Najafi Chermahini introduced a KIT-6 mesoporous silica-supported vanadium and zirconium catalyst for furfural oxidation with H 2 O 2 , which provided a 29.2% yield of maleic acid with 81.2% conversion of furfural in 1 h at 343 K, and a similar mechanism as Scheme was proposed by the authors for maleic acid formation. Clearly, two distinct mechanisms were proposed for furfural oxidation to maleic acid in liquid oxidations by O 2 and H 2 O 2 , respectively.…”

Section: Aliphatic Diacids and Anhydridementioning

confidence: 99%

Catalytic Transformation of the Furfural Platform into Bifunctionalized Monomers for Polymer Synthesis

Zhu

Yin

2021

ACS Catal.

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Furfural is currently industrially produced from raw agricultural materials with almost no limit; however, its market volume is very limited due to its monofunctionalized furan structure. Apparently, the exploration of new catalytic technologies to transform furfural into versatile bifunctionalized monomers for polymer syntheses may substantially open up furfural-based biomass utilizations and partially reduce concerns about the scarcity of the carbon source in the chemical industry caused by the rapid depletion of fossil resources. This Review summarizes the current state of the art of bifunctional monomer development from the furfural platform, including aliphatic diols, diacids and anhydrides, bifunctionalized furans and bifurans, and furan-based bisphenol A analogues. We hope the coming success in catalytic efficiency improvements in these monomer syntheses from the furfural platform with related polymer developments may boost furfural-based hemicellulose utilizations.

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Section: Aliphatic Diacids and Anhydridementioning

confidence: 99%

Catalytic Transformation of the Furfural Platform into Bifunctionalized Monomers for Polymer Synthesis

Zhu

Yin

2021

ACS Catal.

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“…A productivity as high as 61.9 mmol MA g cat –1 h –1 was achieved at 70 °C after only 1 h of reaction in acetonitrile with a H 2 O 2 /furfural mole ratio of 3. Regrettably, the low MA selectivity (36%) rendered this catalytic system less atom-economic . For the reaction mechanism, the vanadium(IV) species interacts with hydrogen peroxide, yielding the hydroxyl radical as shown in Scheme a .…”

Section: Synthesis Of Dicarboxylic Acid From Biomass-derived Feedstocksmentioning

confidence: 99%

Toward Value-Added Dicarboxylic Acids from Biomass Derivatives via Thermocatalytic Conversion

Wei

Lee

2021

ACS Catal.

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Dicarboxylic acids (DCAs) are highly value-added chemicals and intermediates extensively applied in various fields of the chemical industry. Transformation of the renewable and abundant biomass and its derivatives is viewed as a promising and sustainable process for DCA production, thus being paid considerable attention. The present Review provides a summary of recent achievements in the development of catalytic systems for synthesis of DCAs, including oxalic acid, malonic acid, tartronic acid, maleic acid, fumaric acid, succinic acid, adipic acid, glucaric acid, 2,5-furandicarboxylic acid, and terephthalic acid from biomass derivatives in thermocatalytic routes. The performances of catalytic systems are assessed in aspects of reactivity, selectivity toward each DCA, reusability, and operating conditions. The involved reaction pathways and mechanisms are discussed to offer deep insights into DCA formations from biomass derivatives.

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“…In a recent study, Rezaei and coworkers [71]. used vanadyl pyrophosphate and zirconium pyrophosphate particles in the oxidation of furfural to maleic acid.…”

Section: Oxidationmentioning

confidence: 99%

Common Reactions of Furfural to scalable processes of Residual Biomass

Rodrı́guez¹,

Rache²,

Brijaldo³

et al. 2020

Cienc. En Desarro.

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Energy and the environment will always play key roles in society. The climate emergency cannot be ruled out to enable the transition for a clean energy future. Currently, non-renewable energy resources are declining, therefore is important to continuously explore renewable resources. Biomass is a renewable resource that can be applied to reduce climate changes and to accomplhish emission policies. Cellulose is the most abundant type of biomass worldwide, which can be transformed into biofuels and potential building block platform molecules (e.g furfural) throughout biological or chemical methods. Furfural can be synthetized from cellulose using hydrolysis and dehydration reactions. Furfural has a furan ring and carbonyl functional group which makes it an important intermediary to produce higher value-added molecules at industrial level. These molecules include gasoline, diesel and jet fuel. However, furfural can also be transformed by hydrogenation, oxidation, decarboxylation and condensation reactions. The selective hydrogenation of furfural produces furfuryl alcohol, an important industrial compound, which is widely employed in the production of resins, fibers, and is considered an essential product for pharmaceutical applications. On the other hand, the oxidation of furfural produces furoic acid which is appliedin the agrochemical industry, where it is commonly transformed to furoyl chloride which is finally used in the production of drugs and insecticides. The oxidation and reduction of furfural can carry out through heterogeneous and homogeneous catalysis, and biocatalysis. Selectivity is an important issue in furfural hydrogenation and oxidation reactions since different products can be obtained by using monometallic or bimetallic catalysts and/or different catalyst supports. In biocatalysis approach, different enzymes, complete cells, tools of modern biotechnology, DNA sequencing, regulation of metabolic networks, overexpression of genes that encode enzymes of interest and optimization of the cellular properties of the microorganism are used. Herein, a review on the current status of furfuryl alcohol and furoic acid production from furfural by heterogeneous catalysis and biocatalysis has been studied. The stability, selectivity and activity of catalystsalong with the different furfural oxidation and reduction conditions have been pointed out. Additionally, the main enzymes, microorganisms and mechanism involved in the furfural degradation process have also been discussed.

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Furfural oxidation to maleic acid with H2O2 by using vanadyl pyrophosphate and zirconium pyrophosphate supported on well-ordered mesoporous KIT-6

Cited by 32 publications

References 38 publications

Catalytic Transformation of the Furfural Platform into Bifunctionalized Monomers for Polymer Synthesis

Catalytic Transformation of the Furfural Platform into Bifunctionalized Monomers for Polymer Synthesis

Toward Value-Added Dicarboxylic Acids from Biomass Derivatives via Thermocatalytic Conversion

Common Reactions of Furfural to scalable processes of Residual Biomass

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