Furan-based polyesters from renewable resources: Crystallization and thermal degradation behavior of poly(hexamethylene 2,5-furan-dicarboxylate)

Papageorgiou, George Z.; Tsanaktsis, Vasilios; Papageorgiou, Dimitrios G.; Chrissafis, K.; Exarhopoulos, Stylianos; Bikiaris, Dimitrios N.

doi:10.1016/j.eurpolymj.2014.08.031

Cited by 135 publications

(131 citation statements)

References 52 publications

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“…2,5‐Furandicarboxylic acid (H 2 FDCA), a member of the furan family, is symmetric dicarboxylic acids obtained from oxidation both primary alcohol and aldehyde groups of 5‐hydroxymethylfurfural (HMF) . H 2 FDCA is a biomass derived product and considered one of the promising monomers for the synthesis of polyesters, polyamides and polyurethanes . According to the aromatic structure and biologically based origin, the H 2 FDCA can be regarded as an excellent substitute for fossil fuel based monomers such as terephthalic acid (TPA).…”

Section: Introductionmentioning

confidence: 99%

A new dinuclear copper (II) complex of 2,5–Furandicarboxyclic acid with 4(5)‐Methylimidazole as a high potential α‐glucosidase inhibitor: Synthesis, Crystal structure, Cytotoxicity study, and TD/DFT calculations

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Altürk

Sönmez

et al. 2019

Applied Organom Chemis

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A new dinuclear copper (II) complex of 2,5–furandicarboxyclic acid with 4(5)‐methylimidazole, [Cu (FDCA)((4(5)MeI)2]2·2H2O, was synthesized, and its structure characterized by XRD, FT–IR and UV–Vis spectroscopic techniques. The α‐glucosidase inhibition and cytotoxicity study of the synthesized Cu (II) complex were determined by IC50 values. The optimized geometry and vibrational harmonic frequencies for the Cu (II) complex were obtained by using Density Functional Theory (DFT) of HSEh1PBE/6–311++G(d,p)/LanL2DZ level. TD‐DFT/HSEh1PBE/6–311++G(d,p)/LanL2DZ level with CPCM model was applied to examine the electronic spectral properties and major contributions were determined via Swizard program. To investigate linear and nonlinear optical behavior of the synthesized Cu (II) complex, the α, Δα and χ(1)/β, γ and χ(3) parameters called linear/nonlinear optical parameters in gas phase and ethanol solvent were computed at the same level and basis set. Furthermore, molecular electrostatic potential (MEP) surface was determined by using the same level. The docking study of the Cu (II) complex to the binding site of the target protein (the template structure S. cerevisiae isomaltase) is fulfilled. Natural bond orbital (NBO) analysis was used to investigate the hyperconjugative interactions, inter‐ and intra‐molecular bonding and to determine coordination around Cu (II) ion. Finally, present work is the first remarkable scientific report of mixed‐ligand (H2FDCA and 4(5)MeI) Cu (II) complex as novel drug candidate for DM II. It is also determined that microscopic third−NLO parameters for the Cu (II) complex is remarkable.

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Section: Introductionmentioning

confidence: 99%

A new dinuclear copper (II) complex of 2,5–Furandicarboxyclic acid with 4(5)‐Methylimidazole as a high potential α‐glucosidase inhibitor: Synthesis, Crystal structure, Cytotoxicity study, and TD/DFT calculations

Avcı

Altürk

Sönmez

et al. 2019

Applied Organom Chemis

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show abstract

“…Taking the polyesters for example, by varying the type of diols, different polyesters derived from FDCA, such as poly(octylene 2,5-furandicarboxylate) (POF) [12], poly (ethylene 2,5-furandicarboxylate) (PEF) [15,21], poly(propylene 2,5-furandicarboxylate) (PPF) [22], poly(butylene 2,5-furandicarboxylate) (PBF) [23][24][25][26] and poly(hexamethylene 2,5-furandicarboxylate) (PHF) [27], have been synthesized. Among them, PEF might be the most promising one due to its higher glass transition temperature and better mechanical properties.…”

Section: Introductionmentioning

confidence: 99%

Modification of poly(ethylene 2,5-furandicarboxylate) with 1,4-cyclohexanedimethylene: Influence of composition on mechanical and barrier properties

Wang

Liu

Zhang

et al. 2016

Polymer

154

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“…the application range of phthalates is a tendency in the future [6][7][8][9] . Moreover, petroleum shortages and environmental concerns have encouraged extensive researches on chemical products based on renewable resources [10][11][12][13][14] . As a result, there is a growing interest in the use of bio-based plasticizers that are characterized by sustainability, availability and low cost.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and application of a novel environmental plasticizer based on cardanol for poly(vinyl chloride)

Chen

Lü

Wang

et al. 2016

Journal of the Taiwan Institute of Chemical Engineers

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Furan-based polyesters from renewable resources: Crystallization and thermal degradation behavior of poly(hexamethylene 2,5-furan-dicarboxylate)

Cited by 135 publications

References 52 publications

A new dinuclear copper (II) complex of 2,5–Furandicarboxyclic acid with 4(5)‐Methylimidazole as a high potential α‐glucosidase inhibitor: Synthesis, Crystal structure, Cytotoxicity study, and TD/DFT calculations

A new dinuclear copper (II) complex of 2,5–Furandicarboxyclic acid with 4(5)‐Methylimidazole as a high potential α‐glucosidase inhibitor: Synthesis, Crystal structure, Cytotoxicity study, and TD/DFT calculations

Modification of poly(ethylene 2,5-furandicarboxylate) with 1,4-cyclohexanedimethylene: Influence of composition on mechanical and barrier properties

Synthesis and application of a novel environmental plasticizer based on cardanol for poly(vinyl chloride)

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