Fungicidal Activities of 2-Methoxy-2-[2-(benzylideneaminooxymethyl)phenyl]-&lt;i&gt;N&lt;/i&gt;-methylacetamide Derivatives

常男, 市場; 孝己, 村司; 慎司, 鈴木; 俊一, 大塚; 道生, 益子

doi:10.1584/jpestics.27.223

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“…1 ). 1 Accordingly, significant efforts have been devoted to their synthesis. In this context, α-functionalization of carbonyl compounds such as the transition metal-catalyzed insertion of α-diazo carbonyl into O–H bond ( Scheme 1a ), 2,3 has been established as one of the most important methods to construct these structures.…”

Section: Introductionmentioning

confidence: 99%

Facile synthesis of α-alkoxyl amides via scandium-catalyzed oxidative reaction between ynamides and alcohols

et al. 2018

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A novel and efficient scandium-catalyzed oxidative reaction between ynamides and alcohols for the facile synthesis of various a-alkoxyl amides is reported in this paper. The reaction avoids the need for the use of adiazo carbonyls which are unstable and may cause some safety concerns. Instead, by using alkynes as the starting materials, this protocol features readily available substrates, compatibility with a broad range of functional groups, simple procedure, mild reaction conditions, and high chemoselectivity.

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Section: Introductionmentioning

confidence: 99%