Ultracompact chip-integrated all-optical diode is realized experimentally in a plasmonic microstructure, consisting of a plasmonic waveguide side-coupled two asymmetric plasmonic composite nanocavities covered with a multicomponent nanocomposite layer, formed directly in a plasmonic circuit. Extremely large optical nonlinearity enhancement is obtained for the multicomponent nanocomposite cover layer, originating from resonant excitation, slow-light effect, and field enhancement effect. Nonreciprocal transmission was achieved based on the difference in the shift magnitude of the transparency window centers of two asymmetric plasmonic nanocavities induced by the signal light, itself, for the forward and backward propagation cases. An ultralow threshold incident light power of 145 μW (corresponding to a threshold intensity of 570 kW/cm 2 ) is realized, which is reduced by seven orders of magnitude compared with previous reports. An ultrasmall feature size of 2 μm and a transmission contrast ratio of 15 dB are obtained simultaneously.Keywords: plasmonic nanocavity; all-optical diode; plasmon-induced transparency; third-order optical nonlinearity; multicomponent nanocomposite.Ultracompact chip-integrated all-optical diode, possessing unique nonreciprocal transmission properties, is an essential and core component of optical computing system, ultrahigh-speed information processing chips, and optical communication networks [1]. For the practical on-chip integration applications, the all-optical diode should possess the following key characteristics: ultrasmall feature size, ultralow threshold power, high isolation ratio, and on-chip trigger [2,3]. The basic idea of realizing chip-integrated all-optical diode is to break the time-reversal symmetry by using indirect interband photonic transition [4][5][6][7], angular-momentum biasing [8], magneto-optic effect [9-14], third-order optical nonlinearity [15][16][17][18], in dielectric photonic microstructures with broken spatial-reversal symmetry, including asymmetric photonic crystal heterostructures and asymmetric silicon ring resonators [19,20]. The large size of dielectric photonic microstructures limits the practical on-chip integration applications of an all-optical diode [21]. Moreover, owing to the relatively small third-order nonlinear optical susceptibility of conventional organic and semiconductor materials, the threshold operation intensity is as high as GW/cm 2 order for the all-optical dielectric diode realized based on third-order optical nonlinearity [15][16][17][18][19][20]. Plasmonic microstructures possess the unique ability of confining light into deep-subwavelength scale and strong field reinforcement effect, which provides an excellent platform for the realization of nanoscale chipintegrated photonic devices [22]. Various schemes have been proposed to demonstrate chip-integrated all-optical diode in plasmonic microstructures, such as using graded plasmonic chains based on full retardation effect [23,24], magnetized spiral chains of plasmonic e...