Functionalization of the magnetic chitosan support with dipyridylamine as a nitrogen-rich pincer ligand for Pd immobilization and investigation of catalytic efficiency in Sonogashira coupling
“…Whereas, electron-donating groups have an opposite effec on the breaking of C-Br bonding, resulting in low yield (entry 11, 12). For a similar reaction with similar reaction conditions, the novel catalysts prepared in this work show superio comprehensive catalytic performances to other recent Pd heterogeneous catalytic systems [28][29][30][31]. Besides the model reaction, the Pd@polymer/AlMn 0.15 -PM nanocomposite catalysis system can be well extended to the Sonogashira coupling reactions of other aryl halides with phenyl acetylene.…”
Section: Samplesmentioning
confidence: 75%
“…Whereas, electron-donating groups have an opposite effect on the breaking of C-Br bonding, resulting in low yield (entry 11, 12). For a similar reaction with similar reaction conditions, the novel catalysts prepared in this work show superior comprehensive catalytic performances to other recent Pd heterogeneous catalytic systems [28][29][30][31].…”
Montmorillonite clay was modified by pillaring with AlMn oxides in different Al/Mn ratios and intercalation of two kinds of N-containing polymers (i.e., chitosan (CS) and polyvinyl pyrrolidinone (PVP)) chains. The modified pillared montmorillonite clay (PM) showed a rich two-dimensional layered porous structure with tunable parameters, such as large interlayer spacing, high specific area, and large porous volume. They were then used as supports for Pd nanoparticles. As applied in coupling reactions of aryl halides with terminal alkynes, Pd@CS/AlMn-PM showed better comprehensive catalytic performance than Pd@PVP/AlMn-PM. This was mainly attributed to its higher specific area, stronger chelation to Pd species, and better solvent resistance.
“…Whereas, electron-donating groups have an opposite effec on the breaking of C-Br bonding, resulting in low yield (entry 11, 12). For a similar reaction with similar reaction conditions, the novel catalysts prepared in this work show superio comprehensive catalytic performances to other recent Pd heterogeneous catalytic systems [28][29][30][31]. Besides the model reaction, the Pd@polymer/AlMn 0.15 -PM nanocomposite catalysis system can be well extended to the Sonogashira coupling reactions of other aryl halides with phenyl acetylene.…”
Section: Samplesmentioning
confidence: 75%
“…Whereas, electron-donating groups have an opposite effect on the breaking of C-Br bonding, resulting in low yield (entry 11, 12). For a similar reaction with similar reaction conditions, the novel catalysts prepared in this work show superior comprehensive catalytic performances to other recent Pd heterogeneous catalytic systems [28][29][30][31].…”
Montmorillonite clay was modified by pillaring with AlMn oxides in different Al/Mn ratios and intercalation of two kinds of N-containing polymers (i.e., chitosan (CS) and polyvinyl pyrrolidinone (PVP)) chains. The modified pillared montmorillonite clay (PM) showed a rich two-dimensional layered porous structure with tunable parameters, such as large interlayer spacing, high specific area, and large porous volume. They were then used as supports for Pd nanoparticles. As applied in coupling reactions of aryl halides with terminal alkynes, Pd@CS/AlMn-PM showed better comprehensive catalytic performance than Pd@PVP/AlMn-PM. This was mainly attributed to its higher specific area, stronger chelation to Pd species, and better solvent resistance.
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