Functionalization of Tetraphosphido Ligands by Heterocumulenes
Sebastian Hauer,
Gábor Balázs,
Fabian Gliese
et al.
Abstract:Although numerous
polyphosphido complexes have been accessed through
the transition-metal-mediated activation and functionalization of
white phosphorus (P4), the selective functionalization
of the resulting polyphosphorus ligands in these compounds remains
underdeveloped. In this study, we explore the reactions between cyclotetraphosphido
cobalt complexes and heterocumulenes, leading to functionalized P4 ligands. Specifically, the reaction of carbon disulfide (CS2) with [K(18c-6)][(Ar*BIAN)Co(η4-P4)] ([K(18c-6… Show more
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