Functionalised organometallic photoswitches containing dihydropyrene units

Gillespie, Angus A.; Roemer, Max; Jago, David; Sobolev, Alexandre N.; Nealon, Gareth L.; Spackman, Peter R.; Moggach, Stephen A.; Koutsantonis, George A.

doi:10.1039/d3dt02505e

Dalton Trans.

2023

DOI: 10.1039/d3dt02505e

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Functionalised organometallic photoswitches containing dihydropyrene units

Angus A. Gillespie,

Max Roemer,

David Jago

et al.

Abstract: Synthesis of half-sandwich Ru and Fe complexes functionalised with alkynyl dihydropyrenes is described. Unlike the parent DHP ligand, several of the metal alkynyl dihydropyrenes showed evidence of photoswitching as a result of a higher barrier to thermal reversion.

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Toward Practical Single‐Molecule/Atom Switches

Xu,

Gao,

Emusani

et al. 2024

Advanced Science

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Electronic switches have been considered to be one of the most important components of contemporary electronic circuits for processing and storing digital information. Fabricating functional devices with building blocks of atomic/molecular switches can greatly promote the minimization of the devices and meet the requirement of high integration. This review highlights key developments in the fabrication and application of molecular switching devices. This overview offers valuable insights into the switching mechanisms under various stimuli, emphasizing structural and energy state changes in the core molecules. Beyond the molecular switches, typical individual metal atomic switches are further introduced. A critical discussion of the main challenges for realizing and developing practical molecular/atomic switches is provided. These analyses and summaries will contribute to a comprehensive understanding of the switch mechanisms, providing guidance for the rational design of functional nanoswitch devices toward practical applications.

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Toward Practical Single‐Molecule/Atom Switches

Xu,

Gao,

Emusani

et al. 2024

Advanced Science

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show abstract

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Functionalised organometallic photoswitches containing dihydropyrene units

Abstract: Synthesis of half-sandwich Ru and Fe complexes functionalised with alkynyl dihydropyrenes is described. Unlike the parent DHP ligand, several of the metal alkynyl dihydropyrenes showed evidence of photoswitching as a result of a higher barrier to thermal reversion.

Cited by 1 publication

References 81 publications

Toward Practical Single‐Molecule/Atom Switches

Toward Practical Single‐Molecule/Atom Switches

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