A detailed statistical analysis of turbulent flow and heat transfer in eccentric annular duct was performed via direct numerical simulations (DNS) with particular emphasis on the needs of turbulence closure models. A large number of flow characteristics such as components of the Reynolds stress tensor, temperature-velocity correlations and some others were obtained for the first time for such kind of a flow. The results of the paper will serve as a benchmark test case for turbulence modelling, specifically for models intended to be used for flows with partly turbulent regimes.