Fullerene C60 as a New Stationary Phase in Capillary Gas Chromatography

Golovnya, R. V.; Terenina, M. B.; Ruchkina, E. L.; Karnatsevich, V. L.

doi:10.1070/mc1993v003n06abeh000305

Cited by 20 publications

(10 citation statements)

References 14 publications

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“…The optimum dielectric constant range was 0.3-0.8 and the Hildebrand solubility parameter was between 9.0 and 10.0 cal 0.5 /cm 1.5 for obtaining high solubility. Golovnya et al [18] used C 60 as a capillary gas chromatographic stationary phase. They showed that for the retention behavior of alkanes, C 60 was comparable to nonpolar stationary phases such as squalane.…”

Section: Introductionmentioning

confidence: 99%

Multiparameter solubility model of fullerene C60

Huang

2005

Fluid Phase Equilibria

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Section: Introductionmentioning

confidence: 99%

Multiparameter solubility model of fullerene C60

Huang

2005

Fluid Phase Equilibria

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“…A glass capillary column (15 m × 0.29 mm I.D.) was coated with pure C60 (film thickness 0.1 μm) using a high-pressure static method [90]. The thermostable solid C60 phase behaved like the liquid phase squalane in its van der Waals interaction with n -alkanes.…”

Section: Chromatography Of Fullerenes and The Reciprocal Principlementioning

confidence: 99%

The Reciprocal Principle of Selectand-Selector-Systems in Supramolecular Chromatography †

Schurig

2016

Molecules

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Abstract:In selective chromatography and electromigration methods, supramolecular recognition of selectands and selectors is due to the fast and reversible formation of association complexes governed by thermodynamics. Whereas the selectand molecules to be separated are always present in the mobile phase, the selector employed for the separation of the selectands is either part of the stationary phase or is added to the mobile phase. By the reciprocal principle, the roles of selector and selectand can be reversed. In this contribution in honor of Professor Stig Allenmark, the evolution of the reciprocal principle in chromatography is reviewed and its advantages and limitations are outlined. Various reciprocal scenarios, including library approaches, are discussed in efforts to optimize selectivity in separation science.

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“…[60]Fullerene itself may be used as a stationary phase for liquid chromatography (LC) [2,3] or for gas chromatography [4] directly, but its application is strongly limited by its rather low surface area (10 20 m2.g-1), solubility, and other factors. The covalent attachment of [60]fullerene to an inert support with a high surface area appears to be a preferable choice.…”

Section: Introductionmentioning

confidence: 99%

[60] Fulleropyrrolidine functionalized polysiloxane as a stationary phase for capillary gas chromatography

Zeng

Liu

et al. 1999

Chromatographia

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SummaryIn this paper, a new type of [60]fulleropyrrolidine functionalized polysiloxane in which the fullerene moieties were incorporated in the main polysiloxane chain was synthesized the first time and used as a stationary phase for capillary gas chromatography. It demonstrated high column efficiency (2600-2866 plates m -1, on a 250 pm diameter column, for naphthalene k = 3.1-3.2, 120 ~ a wide operational temperature range (90-360 ~ and outstanding thermostability. It can be used at 360 ~ with a baseline drift of 5 -8 x 10-15A. Benzene homologues, aromatic hydrocarbons, polar compounds such as alcohols, esters, ketones, anilines and phthalic diesters can be seperated well on this column.

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Fullerene C60 as a New Stationary Phase in Capillary Gas Chromatography

Cited by 20 publications

References 14 publications

Multiparameter solubility model of fullerene C60

Multiparameter solubility model of fullerene C60

The Reciprocal Principle of Selectand-Selector-Systems in Supramolecular Chromatography †

[60] Fulleropyrrolidine functionalized polysiloxane as a stationary phase for capillary gas chromatography

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