FTIR Emission Spectra, Molecular Constants, and Potential Curve of Ground State GeO

The Radial Hamiltonians for the X1Σ+ and B1Σ+ States of HCl

“…We first described (11) this approach for the ground states of HBr and HI; subsequent applications included LiH (6), CO (12), NaF, LiI, CS, and SiS (7). Similar success was obtained by Bernath and co-workers in applications for GaH (13), AlCl (14), LiH/LiD (15), and GeO (16). Strong arguments (12,14) were advanced in support of the parameterized potential approach, especially in terms of the reliability afforded for extrapolations beyond the range of the data, and the compactness afforded by the analytical model.…”

“…[5] and [16] leads only to a small change in the effective potential, and that this change is negligible in relation to the leading effect of U ad (R). For all practical purposes, then, a consensus has been achieved that the effective hamiltonian can be expressed by the forms given in either Eqs.…”

The Rotational Analysis of the A2Πr–X2Σ+ Band System of MgBr

“…All of the spectra of MgBr were recorded with the modified Bruker IFS 120HR Fourier transform spectrometer (FTS) at University of Waterloo (17). The spectrometer was recently modified to record double-sided interferograms, in order to eliminate lineshape problems associated with the phase correction.…”

ExoMol molecular line lists – XIII. The spectrum of CaO

“…We have represented the ab initio PEC (Khalil et al 2011) analytically using an Extended Morse Oscillator (EMO) function (Lee et al 1999), where the dissociation value was changed to agree with the common value of De=5.99 eV (relative to X 1 Σ + ) and the Te and re values were refined by keeping all other parameters from the Morse exponent unchanged. Due to the limited data our results represent only a possible solution for this state.…”