FT-IR and<sup>29</sup>Si-NMR Studies on UV-Curable DDS-MPTMS/SiO<sub>2</sub>Hybrid Coating

Lin, Juan; Zeng, Xingrong; Youjun, Hou

doi:10.1080/03602550802497974

Cited by 1 publication

(1 citation statement)

References 17 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[10][11][12] In previous papers, we prepared different hyperbranched polyurethane acrylate/ SiO 2 hybrid coatings that had higher thermal stability and better mechanical performance. 13 However, the viscosity of the formulations was higher and the curing rate was lower. This article presents the preparation conditions and mechanical performance of a series of UV-curable hyperbranched polyurethane acrylates (HBPUA) that are characterized by Fourier transform infrared (FTIR) spectroscopy, 1 H nuclear magnetic resonance ( 1 H-NMR) spectroscopy, and gel permeation chromatography (GPC).…”

Section: Introductionmentioning

confidence: 98%

Preparation and characterization of UV-curable hyperbranched polyurethane acrylate

Gao

Zeng

2010

J Coat Technol Res

Self Cite

View full text Add to dashboard Cite

A UV curable complex system with vinyl resin and polyurethane acrylate photo-polymerization was investigated. The UV curing process of complex system was traced by IR. Thermal decomposition temperature of UV cured film for various system were determined by thermogravimetric analysis(TGA). And physical properties of those curing films were analyzed and compared. The results show The results show the thermal decomposition temperature, and alkali resistance and hardness of the product gradually decreased with the increase in the proportion of polyurethane acrylic prepolymer.The vinyl resin pre polymer were synthesized by epoxy resin E-51 and acrylic acid.The polyurethane pre polymer was prepared by the reaction of polyether-1000 and TDI-80 with hydroxyethyl ester as the end capping agent. The two kinds of products were mixed in different proportions, and the vinyl resin was modified by polyurethane. Finally, diluent and photo initiator were added to the UV curing of products. The results showed that the vinyl resin and polyurethane prepolymer were successfully prepared. The properties of the products were evaluated by IR, TGA and other methods. The alkali resistance and hardness of curing films have been tested.

show abstract