Front Cover: Half‐Sandwich Iridium Complexes Bearing a Diprotic Glyoxime Ligand: Structural Diversity Induced by Reversible Deprotonation (Chem. Asian J. 1/2020)

Takamura, Taishin; Harada, Takuya; Furuta, Tatsuro; Ikariya, Takao; Kuwata, Shigeki

doi:10.1002/asia.201901486

Cited by 27 publications

(1 citation statement)

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“…Nitrides with defects have shown many unique functions, where defects in nitrides are detrimental to the electrode or catalytic reactions by working as a recombination center of charge carriers (Van de Walle and Neugebauer, 2004;Wang et al, 2018;Takamura et al, 2020). Reasonable control of defects in nitrides is the key to the excellent performance of these nitrides.…”

Section: Nitrides With Defectsmentioning

confidence: 99%

Advanced Inorganic Nitride Nanomaterials for Renewable Energy: A Mini Review of Synthesis Methods

Xiong

et al. 2021

Front. Chem.

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Inorganic nitride nanomaterials have attracted widespread attention for applications in renewable energy due to novel electrochemical activities and high chemical stabilities. For different renewable energy applications, there are many possibilities and uncertainties about the optimal nitride phases and nanostructures, which further promotes the exploration of controllable preparation of nitride nanomaterials. Moreover, unlike conventional nitrides with bulk or ceramic structures, the synthesis of nitride nanomaterials needs more accurate control to guarantee the target nanostructure along with the phase purity, which make the whole synthesis still a challenge to achieve. In this mini review, we mainly summarize the synthesis methods for inorganic nitride nanomaterials, including chemistry vapor deposition, self-propagation high-temperature synthesis, solid state metathesis reactions, solvothermal synthesis, etc. From the perspective of nanostructure, several novel nitrides, with nanostructures like nanoporous, two-dimensional, defects, ternary structures, and quantum dots, are showing unique properties and getting extensive attentions, recently. Prospects of future research in design and synthesis of functional inorganic nitrides are also discussed.

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Section: Nitrides With Defectsmentioning

confidence: 99%

Advanced Inorganic Nitride Nanomaterials for Renewable Energy: A Mini Review of Synthesis Methods

Xiong

et al. 2021

Front. Chem.

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Mito‐Bomb: Targeting Mitochondria for Cancer Therapy

et al. 2021

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Cancer has been one of the most common life‐threatening diseases for a long time. Traditional cancer therapies such as surgery, chemotherapy (CT), and radiotherapy (RT) have limited effects due to drug resistance, unsatisfactory treatment efficiency, and side effects. In recent years, photodynamic therapy (PDT), photothermal therapy (PTT), and chemodynamic therapy (CDT) have been utilized for cancer treatment owing to their high selectivity, minor resistance, and minimal toxicity. Accumulating evidence has demonstrated that selective delivery of drugs to specific subcellular organelles can significantly enhance the efficiency of cancer therapy. Mitochondria‐targeting therapeutic strategies are promising for cancer therapy, which is attributed to the essential role of mitochondria in the regulation of cancer cell apoptosis, metabolism, and more vulnerable to hyperthermia and oxidative damage. Herein, the rational design, functionalization, and applications of diverse mitochondria‐targeting units, involving organic phosphine/sulfur salts, quaternary ammonium (QA) salts, peptides, transition‐metal complexes, guanidinium or bisguanidinium, as well as mitochondria‐targeting cancer therapies including PDT, PTT, CDT, and others are summarized. This review aims to furnish researchers with deep insights and hints in the design and applications of novel mitochondria‐targeting agents for cancer therapy.

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Adaptive σ‐Aromaticity in an Unsaturated Three‐Membered Ring

Huang

Dai

Zhu

2020

Chemistry An Asian Journal

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Based on Hückel's and Baird's rules, species are aromatic either in the lowest singlet state (S 0) or the lowest triplet state (T 1) only. Thus, species with adaptive aromaticity (with aromaticity in both the S 0 and T 1 states) is particularly rare. On the other hand, σ-aromaticity in the T 1 state has been underdeveloped, let alone adaptive σ-aromaticity. Herein, via various aromaticity indices including NICS, ACID and EDDB, we demonstrate adaptive σ-aromaticity in an unsaturated three-membered ring, which is a traditional area [a

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Front Cover: Half‐Sandwich Iridium Complexes Bearing a Diprotic Glyoxime Ligand: Structural Diversity Induced by Reversible Deprotonation (Chem. Asian J. 1/2020)

Cited by 27 publications

References 0 publications

Advanced Inorganic Nitride Nanomaterials for Renewable Energy: A Mini Review of Synthesis Methods

Advanced Inorganic Nitride Nanomaterials for Renewable Energy: A Mini Review of Synthesis Methods

Mito‐Bomb: Targeting Mitochondria for Cancer Therapy

Adaptive σ‐Aromaticity in an Unsaturated Three‐Membered Ring

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