From water molecules mobility to water-resistance of swollen oriented and non-oriented cellulose nanofibrils cryogels
Rouillon Charlie,
Foucat Loïc,
Chaunier Laurent
et al.
Abstract:The development of porous, water-resistant cellulose-based materials with shape-recovery performance requires control of the swelling behaviour of these materials. In this context, TEMPO-oxidized CNF (CNFt) cryogels, were prepared by non-directional (ND) and unidirectional (UD) freezing step followed by freeze-drying to obtain lightweight porous materials (22.6 kg m-3 and 98% air content), CNFt-ND ou CNFt-UD, with different pore morphologies. Indeed, honeycomb-like or lamellar structures were obtained as evide… Show more
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