From Vanillin to Concrete Plasticizers: An Innovative Path through ADMET Polymerization
Damien Breilly,
Sami Fadlallah,
Amandine Flourat
et al.
Abstract:This study describes innovative lignin-based superplasticizers for concrete, focusing on two crucial features: (i) chelation capabilities (e.g., geminal diacids for binding with calcium ions), and (ii) repulsive methoxy polyethylene glycol (MPEG) chains (for better water solubility and particle repulsion). Starting from vanillin, the synthesis of the monomers relies on three key reactions: enzymatic dimerization, Williamson etherification, and Knoevenagel condensation. These monomers are then polymerized throu… Show more
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